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thanks: Current address: Faculty of Science and Technology, Keio University, Yokohama, Japan

Ashkin-Teller phase transition and multicritical behavior in a classical monomer-dimer model

Satoshi Morita smorita@keio.jp Institute for Solid State Physics, The University of Tokyo, Kashiwa, Chiba 277-8581, Japan    Hyun-Yong Lee Department of Applied Physics, Graduate School, Korea University, Sejong 30019, Korea Division of Display and Semiconductor Physics, Korea University, Sejong 30019, Korea Interdisciplinary Program in E·ICT-Culture-Sports Convergence, Korea University, Sejong 30019, Korea    Kedar Damle Department of Theoretical Physics, Tata Institute of Fundamental Research, Mumbai 400 005, India    Naoki Kawashima Institute for Solid State Physics, The University of Tokyo, Kashiwa, Chiba 277-8581, Japan Trans-scale Quantum Science Institute, The University of Tokyo, Bunkyo-ku, Tokyo 113-0033, Japan
Abstract

We use Monte Carlo simulations and tensor network methods to study a classical monomer-dimer model on the square lattice with a hole (monomer) fugacity zz, an aligning dimer-dimer interaction uu that favors columnar order, and an attractive dimer-dimer interaction vv between two adjacent dimers that lie on the same principal axis of the lattice. The Monte Carlo simulations of finite size systems rely on our grand-canonical generalization of the dimer worm algorithm, while the tensor network computations are based on a uniform matrix product ansatz for the eigenvector of the row-to-row transfer matrix that work directly in the thermodynamic limit. The phase diagram has nematic, columnar order and fluid phases, and a nonzero temperature multicritical point at which all three meet. For any fixed v/u<v/u<\infty, we argue that this multicritical point continues to be located at a nonzero hole fugacity zmc(v/u)>0z_{\rm mc}(v/u)>0; our numerical results confirm this theoretical expectation but find that zmc(v/u)0z_{\rm mc}(v/u)\to 0 very rapidly as v/uv/u\to\infty. Our numerical results also confirm the theoretical expectation that the corresponding multicritical behavior is in the universality class of the four-state Potts multicritical point on critical line of the two-dimensional Ashkin-Teller model.

I Introduction

Dimer models provide interesting examples of entropy-dominated physics [1]. On planar graphs in the fully-packed limit (i.e., with hole fugacity set to zero), they are exactly solvable by Pfaffian methods[2, 3, 4]. These methods allow for a detailed characterization of the critical power law correlations of such fully packed dimer models on the square and honeycomb lattices [5]. This critical behavior also admits an interesting description in terms of a coarse-grained action for a fluctuating height field [1].

The analogous fully packed dimer model in three dimensions as well as two-dimensional bilayer models are not exactly solvable even at full packing, nor are related models with an admixture of hard squares. Several such models have been studied using numerical simulations and coarse-grained effective field theory ideas [6, 7, 8, 9]. Connections to the physics of quantum dimer models [10] and resonating valence bond wave functions [11, 12, 13] have also been explored [14, 15].

Interactions and nonzero hole fugacity also preclude the possibility of an exact solution even in the simple square lattice case. Nevertheless, the phase diagram on the square lattice in the presence of nonzero hole fugacity zz and an aligning interaction uu that favors two parallel dimers on a square plaquette has been studied in detail using numerical simulations [16, 17, 18]. These studies reveal that the aligning interactions drive a transition to columnar order at low temperature TT and fugacity zz. In the columnar ordered phase, both lattice rotational symmetry and translational symmetry are spontaneously broken, and almost all dimers align in the same direction.

In this system, the transition from this columnar ordered state to the dilute high-temperature dimer fluid has a continuously varying correlation length exponent ν\nu, although the anomalous exponent associated with the columnar order parameter remains fixed at η=1/4\eta=1/4 as long as the transition remains second-order in nature [17, 18]. For temperatures below a tricritical value, the transition turns first order [17, 18]. In the regime with a continuously varying correlation length exponent ν\nu, long distance properties are controlled by the physics of the Ashkin-Teller fixed line [19, 20, 21], for which the value of ν\nu serves as a convenient universal coordinate [7]. Indeed, this particular microscopic realization of Ashkin-Teller criticality is described by the portion of the Ashkin-Teller fixed line that starts at its Kosterlitz-Thouless endpoint (corresponding to the transition in the fully packed dimer model, with ν\nu formally equal to infinity) and continues on to the four-state Potts point (corresponding to the tricritical transition of this dimer model, with ν=2/3\nu=2/3) on this fixed line [17, 18].

In related work [22], Papanikolaou et al also studied the effect of an additional dimer interaction vv that competes with the aligning interaction uu and hole fugacity zz on the square lattice. The additional interaction represents an attraction between two adjacent dimers on the same principal axis of the square lattice and favors nematic order. In such a nematic state, lattice translation symmetry is preserved, but the symmetry of rotations by π/2\pi/2 is spontaneously broken. As a result, (NhNv)2L4\langle(N_{h}-N_{v})^{2}\rangle\sim L^{4} in the thermodynamic limit, where NhN_{h} is the number of horizontal dimers, NvN_{v} is the number of vertical dimers, and the angular brackets denote the equilibrium average. The presence of such a state at low enough temperature and small enough hole fugacity zz was also rigorously established [23, 24].

Consequently, the phase diagram in the presence of both interactions uu and vv is rich, and supports three different phases at nonzero hole density: a dilute fluid phase, a nematic phase, and a columnar ordered phase. Previous work [22] characterized the phase diagram in the TT-zz plane in some detail. This analysis led to the following conclusion [22]: When both interactions are nonzero and compete with each other, the transition from the low zz low TT columnar solid to the fluid proceeds in two steps, an Ising transition from columnar order to nematic order, and a second Ising transition from nematic order to fluid. In this scenario [22] for the phase diagram in the zz-TT plane, there are thus two Ising lines emerging from the z=0z=0 Kosterlitz-Thouless transition point when vv and uu compete with each other. In the v/uv/u\to\infty limit, the first of these pivots coincides with the z=0z=0 temperature axis of the zz-TT phase diagram, rendering the low-emperature columnar order unstable to infinitesimal zz.

Having two Ising transition lines emanate from the Kosterlitz-Thouless transition point on the z=0z=0 temperature axis throws up an interesting puzzle when considered from the point of view the coarse-grained field theory ideas used earlier in closely related contexts [7, 18, 17]. At issue is the fact that the Kosterlitz-Thouless point on the z=0z=0 axis at T=TKTT=T_{\rm KT} is expected to continue on to an Ashkin-Teller line TAT(z)T_{\rm AT}(z) as one turns on a small zz and lowers the temperature slightly.

This fits in with the fact that Kosterlitz-Thouless criticality is known to emerge as the limiting behavior at one end of the Ashkin-Teller line when ν\nu\to\infty as this end point is approached. Additionally, it is also well-known that if a line of Ashkin-Teller transitions bifurcates into two Ising lines at a multicritical point, this multicritical point is expected to have four-state Potts symmetry. As a result, one expects that the correlation length exponent tends to ν=2/3\nu=2/3 as this point is approached along the Ashkin-Teller line [20, 25, 21].

Having two Ising transition lines emanate from the Kosterlitz-Thouless transition point on the z=0z=0 temperature axis would violate both these expectations. Resolving this puzzle is our principal motivation for revisiting this phase diagram with a pair of complementary techniques, namely, tensor network (TN) computations and large-scale Monte Carlo (MC) simulations using our grand-canonical generalization of the dimer worm algorithm [17, 26, 27].

The tensor network computations use a matrix product operator representation of the row-to-row transfer matrix to obtain a variational uniform matrix product (uMPS) approximation to its top eigenvector (with largest eigenvalue) [28, 29, 30, 31]. This computational method allows efficient scans of large swathes of the phase diagram as well as direct determination of the central charge and scaling dimensions at critical points. Since it works directly in the thermodynamic limit, the accuracy is only limited by the systematic error associated with the finite internal bond dimension for the tensors used in the matrix product representation; this error can be rendered negligible by choosing a large enough bond dimension. In contrast, the MC results only have statistical sampling errors, but include finite-size effects. We comment on the conventional transfer matrix method on a stripe. Although it can be applied to the monomer-dimer model, the width of a stripe is limited because the size of the transfer matrix grows exponentially [16, 17]. Since the maximum width is much smaller than the correlation length obtained by our simulations near the critical point, we do not adopt this method.

In the next section, we define the monomer-dimer model. In Sec. III, we explain the numerical methods used in this paper. Our numerical results are shown in Sec. V. The last section is devoted to discussion and conclusions.

Refer to caption
Figure 1: A typical configuration of dimers and monomers. Our model has two kinds of dimer-dimer attractive interactions, uu and vv. A monomer has the chemical potential μ\mu.

II Monomer-Dimer Model

We consider a classical hard-core monomer-dimer model with two kinds of attractive dimer-dimer interactions on the square lattice. The classical Hamiltonian in the grand canonical ensemble is given as

H=𝒓α=x,y{unα(𝒓)nα(𝒓+𝒆βα)+vnα(𝒓)nα(𝒓+2𝒆α)}μ𝒓nm(𝒓).H=-\sum_{\bm{r}}\sum_{\alpha=x,y}\bigl{\{}u\,n_{\alpha}(\bm{r})\,n_{\alpha}(\bm{r}+\bm{e}_{\beta\neq\alpha})\\ +v\,n_{\alpha}(\bm{r})\,n_{\alpha}(\bm{r}+2\bm{e}_{\alpha})\bigr{\}}-\mu\sum_{\bm{r}}\,n_{\text{m}}(\bm{r}). (1)

Here, nα(𝒓)n_{\alpha}(\bm{r}) denotes the dimer occupation number of a link between neighboring sites, 𝒓\bm{r} and 𝒓+𝒆α\bm{r}+\bm{e}_{\alpha}, and nm(𝒓)n_{\text{m}}(\bm{r}) is the monomer occupation number at a site 𝒓\bm{r}. These occupation numbers take the value 0 or 11, and should satisfy nx(𝒓)+ny(𝒓)+nx(𝒓𝒆x)+ny(𝒓𝒆y)+nm(𝒓)=1n_{x}(\bm{r})+n_{y}(\bm{r})+n_{x}(\bm{r}-\bm{e}_{x})+n_{y}(\bm{r}-\bm{e}_{y})+n_{\text{m}}(\bm{r})=1 because of the hard-core constraint.

Refer to caption
Figure 2: A typical monomer-dimer configuration of the (a) columnar ordered, (b) nematic, and (c) disordered fluid phases. These are a part of snapshots generated by the MC simulations of the L=256L=256 system at (u,v,z)=(0.1,0.9,0.2)(u,v,z)=(0.1,0.9,0.2). A color of dimers corresponds to a value of the local order parameter Eqs. (9) and (11). Blue, orange, green and purple dimers have (Ψcol(𝒓),Ψnem(𝒓))=(1,1)(\Psi_{\text{col}}(\bm{r}),\Psi_{\text{nem}}(\bm{r}))=(1,1), (1,1)(-1,1), (i,1)(i,-1) and (i,1)(-i,-1), respectively. Monomers are indicated by a empty site.

The uu term in the first term of Eq. (1) is the interaction between two dimers on a plaquette. On the other hand, the vv term acts on two adjacent dimers aligning in the dimer direction (Fig. 1). We call the former the plaquette interaction and the latter the dimer-aligning interaction as well as Ref. [22]. We assume that uu and vv are non-negative, that is, both the interactions are attractive. The last term of Eq. (1) is the chemical potential of monomers. The fugacity of a monomer at the temperature TT is defined as zeβμz\equiv e^{\beta\mu}, where β=1/T\beta=1/T is the inverse temperature. In this paper, we set u+v=1u+v=1 as a unit of energy so that the perfectly columnar ordered state at full packing has a constant energy per site, e=(u+v)/2e=-(u+v)/2.

When the plaquette interaction uu is sufficiently large, the columnar ordered phase appears. This phase spontaneously breaks the symmetry of lattice rotations about a site, as well as lattice translational symmetry along one principal axis. In contrast, in the nematic phase which is favored by the vv term, the system spontaneously choses to have macroscopically more dimers of one orientation over the other. Translational symmetries along both principal axes are preserved, but the system spontaneously breaks the symmetry of lattice rotations about a site.

Typical configurations of three phases are shown in Fig. 2. These are generated by the MC simulations at v=0.9v=0.9 and z=0.2z=0.2, using the method described in the next section for three temperatures, T=0.65T=0.65, 0.750.75, and 0.850.85, which correspond respectively to the columnar ordered, nematic and disordered fluid phases. From this depiction, it is clear that the nematic phase breaks the lattice rotational symmetry but does not break translational symmetry, while the columnar state breaks both lattice translation symmetry and rotational symmetry.

III Methods

As mentioned in Introduction, our computational study of this monomer-dimer model uses complementary methods. One employs our grand-canonical generalization of the dimer worm algorithm to perform Monte Carlo simulations, while the other uses tensor network methods. Below, we summarize each in turn.

III.1 Monte Carlo method

The usual dimer worm algorithm [27, 26, 17] provides a rejection-free nonlocal update scheme for interacting dimer models at full-packing. Here, we build on ideas developed in Ref. 32 to generalize this dimer worm algorithm and obtain an efficient grand-canonical algorithm for the monomer-dimer model at nonzero monomer fugacity. In the first step of our grand-canonical scheme, one chooses at random a site jinitj_{\rm init} of the lattice. There are two possibilities at this first step: either the initially chosen site jinitj_{\rm init} has a monomer on it, or it is covered by a dimer. Let us consider each in turn.

Refer to caption
Figure 3: The label ss labels the different allowed states of a site in our monomer-dimer model. Other dimer states (s=2,3,4s=2,3,4) not shown here are generated by the counter-clockwise 9090^{\circ} rotations. The label σ\sigma (σ\sigma^{\prime}) labels the different entrance (exit) configurations corresponding to a pivot, as defined in our grand-canonical worm algorithm. In the latter context of the worm algorithm, the configurations shown provide a pictorial illustration of the local information needed for calculating the reduced weights given in Eq. (3), which enter the detailed balance constraint equations Eq. (2). Thus entrance/exit σ=0\sigma=0 is schematically depicted with two monomers at the pivot in question to emphasize that the corresponding reduced weight is z2z^{2}, not zz. This is appropriate since entrance/exit σ=0\sigma=0 (σ=0\sigma^{\prime}=0) corresponds to a configuration that has one less dimer compared to the configurations associated with other entrances/exits.

If jinitj_{\rm init} has a monomer on it, we have five options at our disposal. The first four options consist of placing a dimer connecting the initial site to one of its four neighbors. The fifth option is to exit without doing anything. Each of these possibilities is assigned a probability from a probability table. We will discuss the construction of this probability table in some detail below. For now we simply introduce some language that will subsequently be useful in describing the construction of this probability table: the initial site is our first “pivot” site π0\pi_{0}, which we have “entered” from the “entry” σ0=0\sigma_{0}=0, i.e. from “outside the lattice” (Fig. 3). Aborting our attempted worm move at this step itself without doing anything corresponds to “exiting the pivot” π0\pi_{0} via “exit” σ0=0\sigma^{\prime}_{0}=0. On the other hand, if we opt to place a dimer connecting the pivot π0\pi_{0} to its kk-th neighbor, this option corresponds to exiting the pivot via exit σ0=k\sigma^{\prime}_{0}=k (so kk can take on values from 1 to 4). If the chosen exit is σ00\sigma^{\prime}_{0}\neq 0 , we now move to the site corresponding to the chosen exit and continue the construction.

Before we describe what is done next, we need to specify the procedure to be used if the initially chosen site jinitj_{\rm init} has a dimer covering it. In this case, one walks to the other end of this dimer; the site covered by this other end becomes our first pivot π0\pi_{0}, which we have “entered” from the entry σ0\sigma_{0} corresponding to jinitj_{\rm init}. Now, the choices available are again five in number: One can delete this dimer that connects the pivot site π0\pi_{0} to the entrance site j0j_{0}. This introduces two monomers in the system and concludes the worm move. As before, this corresponds to “exiting” the first pivot π0\pi_{0} via exit σ0=0\sigma^{\prime}_{0}=0. Or, one can pivot the dimer covering π0\pi_{0} so that it now connects π0\pi_{0} to its kk-th neighbor. If one of these latter four options is chosen, we say the pivot π0\pi_{0} is exited via exit number σ0=k\sigma^{\prime}_{0}=k, and we move to the site corresponding to the chosen exit to proceed further as described below.

At this stage of our worm construction, we are at the site corresponding to exit σ0\sigma^{\prime}_{0} of the previous pivot, having arrived there because we chose to place a dimer connecting the previous pivot point π0\pi_{0} to this exit site. If this site does not already have another dimer covering it, we have reached an allowed configuration and the worm move ends. On the other hand, if this exit site does have another dimer already covering it, this site becomes the current “overlap site” o0o_{0}. We now walk along this pre-existing dimer from o0o_{0} to its other end. The site at this other end becomes our next pivot site π1\pi_{1}, which has been “entered” via entry number σ1\sigma_{1} that corresponds to the overlap site o0o_{0}.

At this step, there are again five choices for σ1\sigma^{\prime}_{1}, the exit to be used to exit the current pivot site π1\pi_{1}. As before, exit σ1=0\sigma^{\prime}_{1}=0 corresponds to deleting the dimer covering the current pivot site π1\pi_{1}. If this is chosen, the worm move ends. On the other hand, exits numbered σ1=1\sigma^{\prime}_{1}=1 through σ1=4\sigma^{\prime}_{1}=4 correspond to pivoting the dimer covering π1\pi_{1} so that it now connects π1\pi_{1} to the site corresponding to σ1\sigma^{\prime}_{1}. If this exit site does not already have a dimer covering it, we have reached an allowed configuration and the move ends. Otherwise, this exit site becomes the next overlap site o1o_{1}, and the procedure is repeated.

It is easy to see that this worm construction yields a valid rejection-free algorithm if we choose the probability table PσσP_{\sigma\rightarrow\sigma^{\prime}} for transition probabilities in a way that it satisfies local detailed balance at each step. This amounts to requiring that the probability obeys the constraint equations:

ωσPσσ=ωσPσσ.\omega_{\sigma}P_{\sigma\rightarrow\sigma^{\prime}}=\omega_{\sigma^{\prime}}P_{\sigma^{\prime}\rightarrow\sigma}. (2)

Here, PσσP_{\sigma\rightarrow\sigma^{\prime}} is the conditional probability for exiting a pivot via exit σ\sigma^{\prime} given that we have entered it via entrance σ\sigma, PσσP_{\sigma^{\prime}\rightarrow\sigma} is the conditional probability for the reverse process, and the weights ωσ\omega_{\sigma} and ωσ\omega_{\sigma^{\prime}} represent the Boltzmann weights of the configurations corresponding to the choices σ\sigma and σ\sigma^{\prime}, respectively. These Boltzmann weights are to be calculated ignoring the violation of the hard-core constraint on dimers in the configurations that arise during the worm construction.

The simplest choice of solution is the heat-bath solution (sometimes called the Gibbs sampler) given as Pσσ=ωσ/σωσP_{\sigma\rightarrow\sigma^{\prime}}=\omega_{\sigma^{\prime}}/\sum_{\sigma^{\prime}}\omega_{\sigma^{\prime}}. In practice, we use the iterative Metropolized Gibbs sampler to reduce the bounce process [33], i.e., reduce the magnitude of the diagonal elements of the probability table. Note also that the computation of the weights ωσ\omega_{\sigma} and ωσ\omega_{\sigma^{\prime}} is simplified by the fact that they only differ due to factors arising from the contribution of the immediate neighborhood of the pivot. Since the equation set is homogenous, we can cancel all common factors to define reduced weights that only depend on the local environment of the pivot, and use these in Eq. (2).

These reduced weights can be written as

ωσ=z2δσ,0+eβ(un+vm)(1δσ,0)\omega_{\sigma}=z^{2}\delta_{\sigma,0}+e^{\beta(un+vm)}(1-\delta_{\sigma,0}) (3)

where nn (mm) denotes the number of nearest neighbor dimers parallel in the transverse (longitudinal) direction to the dimer that covers the pivot when the configuration corresponds to entrances/exits σ0\sigma\neq 0. These numbers n,m{0,1,2}n,m\in\{0,1,2\} can be calculated by checking the direction of dimers on eight sites around 𝒓h\bm{r}_{\text{h}}, that is, 𝒓h±𝒆x\bm{r}_{\text{h}}\pm\bm{e}_{x}, 𝒓h±𝒆y\bm{r}_{\text{h}}\pm\bm{e}_{y}, 𝒓h±2𝒆x\bm{r}_{\text{h}}\pm 2\bm{e}_{x}, 𝒓h±2𝒆y\bm{r}_{\text{h}}\pm 2\bm{e}_{y}. The number of valid configurations in these eight sites is 6508965089, much smaller than 58=3906255^{8}=390625.

The factor of z2z^{2} in the first term of Eq. (3) reflects the fact that configuration σ=0\sigma=0 has one fewer dimer, i.e., two additional holes (monomers) in comparison with the configurations with σ0\sigma\neq 0.

Finally, we note for completeness that this worm construction and its detailed balance property generalizes straightforwardly to lattices with arbitrary coordination number. The “out-of-plane” entrance/exit in the general case is numbered 0, and the other entrances/exits are numbered from 11 to ncn_{c}, where ncn_{c} is the coordination number of the pivot site in question (ncn_{c} can be different for different sites, and there is thus no restriction of regularity for this algorithm to remain valid)

Using this algorithm, we perform the MC simulations of N=L×LN=L\times L systems with periodic boundary conditions for system size LL up to L=512L=512. The number of the worm updates nwn_{w} used per Monte Carlo step is chosen for each set of control parameters to be such that nwlw=Nn_{w}\langle l_{w}\rangle=N, lw\langle l_{w}\rangle is the mean number of sites visited during the construction of a single worm. We perform 103×N10^{3}\times N worm updates to estimate lw\langle l_{w}\rangle and to thermalize the system before measuring physical quantities. With this convention defining a MC step, we ensure that we obtain at least 2×1062\times 10^{6} MC configurations of the system from which we can calculate equilibrium properties.

III.2 Tensor network method

The tensor network representation of our model is based on the singular value decomposition of the local Boltzmann weight on a bond. The partition function is rewritten as the contraction of the tensor network,

Z=tTriA.Z=\text{tTr}\bigotimes_{i}A. (4)

The tensor AA is located on sites of the square lattice and has four indices representing links to the nearest neighbor sites. An element of AA has the form

Axyxy=s=04(Xr)sx(Xl)sx(Xt)sy(Xb)syYs,A_{xyx^{\prime}y^{\prime}}=\sum_{s=0}^{4}(X_{r})_{sx}(X_{l})_{sx^{\prime}}(X_{t})_{sy}(X_{b})_{sy^{\prime}}Y_{s}, (5)

where ss denotes the local configuration at a site as shown in Fig. 3. The matrices XX’s are determined by the singular value decomposition of the local Boltzmann weight on a bond. The Boltzmann weight on a horizontal bond is represented as a 5×55\times 5 matrix,

Wh=(111010001011eβu/2011eβv1011110eβu/2),W_{h}=\begin{pmatrix}1&1&1&0&1\\ 0&0&0&1&0\\ 1&1&e^{\beta u/2}&0&1\\ 1&e^{\beta v}&1&0&1\\ 1&1&1&0&e^{\beta u/2}\\ \end{pmatrix}, (6)

where the row (column) index of WhW_{h} corresponds to a state at 𝒓\bm{r} (𝒓+𝒆x\bm{r}+\bm{e}_{x}), respectively. Elements with a value of zero indicate a configuration prohibited by the hard-core constraint. The singular value decomposition, Wh=UhShVhTW_{h}=U_{h}S_{h}V_{h}^{T}, defines XrUhSh1/2X_{r}\equiv U_{h}S_{h}^{1/2} and XlVhSh1/2X_{l}\equiv V_{h}S_{h}^{1/2}. We note that UhU_{h} and VhV_{h} can be chosen to be real orthogonal 5×55\times 5 matrices since WhW_{h} is a real square matrix. Similarly we obtain the Boltzmann weight on a vertical bond between 𝒓\bm{r} (row) and 𝒓+𝒆y\bm{r}+\bm{e}_{y} (column) as

Wv=(111101eβu/211000001111eβu/2011eβv10)=UvSvVvT,W_{v}=\begin{pmatrix}1&1&1&1&0\\ 1&e^{\beta u/2}&1&1&0\\ 0&0&0&0&1\\ 1&1&1&e^{\beta u/2}&0\\ 1&1&e^{\beta v}&1&0\\ \end{pmatrix}=U_{v}S_{v}V_{v}^{T}, (7)

and we define XtUvSv1/2X_{t}\equiv U_{v}S_{v}^{1/2} and XbVvSv1/2X_{b}\equiv V_{v}S_{v}^{1/2}. The chemical potential of a monomer acts as the external field and gives the corresponding on-site factor as

Ys=zδs,0+(1δs,0).Y_{s}=z\,\delta_{s,0}+(1-\delta_{s,0}). (8)

The first term has the factor of zz in contrast to Eq. (3). The former corresponds to the Boltzmann weight for valid configurations of our monomer-dimer model, while tha latter is for extended configurations containing one doubly occupied site.

The row-to-row transfer matrix with infinite width is represented as a uniform matrix product operator with a local tensor AA. Using the variational uniform matrix product state algorithm (VUMPS) [28, 29, 30, 31], we calculate the eigenvector corresponding to the largest eigenvalue of the transfer matrix. The uniform matrix product state (uMPS) obtained in this way approximates this eigenvector with accuracy that is controlled by the bond dimension χ\chi of the uMPS. We increase χ\chi up to 128128 to ensure sufficient accuracy. In practice, we assume that the uMPS has a 2×22\times 2 unit-cell structure [31] as is appropriate for a description of the columnar ordered state. After calculating the horizontal uMPS in this way, we also calculate the vertical uMPS, which approximates the corresponding eigenvector of the column-to-column transfer matrix. A good initial guess for the vertical uMPS can be given by the fixed point tensor of the horizontal uMPS [28]. We have confirmed that the physical quantities calculated from the horizontal and vertical uMPS agree with each other to machine precision even in the ordered phases.

IV Observables and interpretation

We now summarize the definitions and physical significance of the various observables of interest to us in this problem, and indicate how they may be accessed in either of the computational methods we use.

Refer to caption
Figure 4: Phase diagram at z=0.2z=0.2 and u+v=1u+v=1 calculated by the TN simulation. The nematic phase exists between diamond and square symbols. The transition temperature between the columnar and nematic phases becomes zero at v=1v=1. The finite bond-dimension effect is smaller than the symbol size.

IV.1 The order parameters and Binder ratios

We detect columnar order using a complex order parameter constructed from the following local order parameter field defined at each site 𝒓=(rx,ry)\bm{r}=(r_{x},r_{y}) as

Ψcol(𝒓)(1)rx{nx(𝒓)nx(𝒓𝒆x)}+i(1)ry{ny(𝒓)ny(𝒓𝒆y)}.\Psi_{\text{col}}(\bm{r})\equiv(-1)^{r_{x}}\left\{n_{x}(\bm{r})-n_{x}(\bm{r}-\bm{e}_{x})\right\}\\ +i\,(-1)^{r_{y}}\left\{n_{y}(\bm{r})-n_{y}(\bm{r}-\bm{e}_{y})\right\}. (9)

The corresponding order parameter,

mcol1N𝒓Ψcol(𝒓),m_{\text{col}}\equiv\frac{1}{N}\sum_{\bm{r}}\Psi_{\text{col}}(\bm{r}), (10)

takes ±1\pm 1 or ±i\pm i when the state has the complete columnar order.

Nematic order, which breaks the symmetry of π/2\pi/2 rotations, can be detected by comparing the number of horizontal and vertical dimers. With this motivation, we define the local nematic order parameter field as

Ψnem(𝒓)nx(𝒓)+nx(𝒓𝒆x)ny(𝒓)ny(𝒓𝒆y),\Psi_{\text{nem}}(\bm{r})\equiv n_{x}(\bm{r})+n_{x}(\bm{r}-\bm{e}_{x})-n_{y}(\bm{r})-n_{y}(\bm{r}-\bm{e}_{y}), (11)

The corresponding order parameter,

mnem1N𝒓Ψnem(𝒓)=2N𝒓{nx(𝒓)ny(𝒓)},m_{\text{nem}}\equiv\frac{1}{N}\sum_{\bm{r}}\Psi_{\text{nem}}(\bm{r})=\frac{2}{N}\sum_{\bm{r}}\left\{n_{x}(\bm{r})-n_{y}(\bm{r})\right\}, (12)

takes on values ±1\pm 1 both in the nematic and columnar states.

The corresponding Binder ratios [34] are defined in the usual way:

Ucol|mcol|4|mcol|22,Unemmnem4mnem22.U_{\text{col}}\equiv\frac{\left<|m_{\text{col}}|^{4}\right>}{\left<|m_{\text{col}}|^{2}\right>^{2}},\quad U_{\text{nem}}\equiv\frac{\left<m_{\text{nem}}^{4}\right>}{\left<m_{\text{nem}}^{2}\right>^{2}}. (13)

As is well-known, the Binder ratios converge in the ordered phase to 11 as the denominator and numerator take on the same limiting value in the thermodynamic limit. On the other hand, in a phase without symmetry breaking, the limiting value depends on the nature of fluctuations of the order parameter. UcolU_{\text{col}} in the nematic and UnemU_{\text{nem}} in the disordered fluid phase are both expected to converge to 33 in the thermodynamic limit because the fluctuations of the corresponding order parameters obey a one-dimensional Gaussian distribution in these regimes. On the other hand, Ucol2U_{\text{col}}\rightarrow 2 in the disordered fluid phase because the fluctuations of mcolm_{\text{col}} obey a two-dimensional Gaussian distribution. We note that the conventional and Ising definition of the Binder parameter for the frustrated Ising model discussed in Ref. [35] correspond UcolU_{\text{col}} and UnemU_{\text{nem}}, respectively. Since the Binder ratio is a dimensionless quantity in the sense of the renormalization group, curves that represent the dependence of a Binder ratio on a control parameter (zz or TT) for systems of different sizes LL are all expected to cross at the critical value of the control parameter. This allow us to locate the phase transitions involving loss of order in a convenient way.

Refer to caption
Figure 5: Phase diagram on the TTzz plane obtained by the TN simulation with χ=128\chi=128. The open (filled) symbols with the solid (dashed) line indicate transition points at v=0.9v=0.9 (0.80.8) with u=1vu=1-v. The direct phase transition between the columnar ordered and disordered fluid phases is shown by a blue circle as well as Fig. 4. The inset is a magnified view for v=0.9v=0.9.

IV.2 Correlation length and entanglement entropy

The correlation length is obtained as

ξ=2ln(λ1/λ0)\xi=-\frac{2}{\ln(\lambda_{1}/\lambda_{0})} (14)

where λ0\lambda_{0} (λ1\lambda_{1}) is the (second) largest eigenvalue of the transfer matrix defined by the uMPS. We note that the uMPS is always normalized such that λ0=1\lambda_{0}=1, and the factor 22 comes from the unit-cell size of the uMPS. Since we calculate the uMPS in both the horizontal and vertical directions, two kinds of correlation length exist in a phase that breaks the symmetry of lattice rotations. The “transverse” correlation length ξ\xi_{\perp} is measured along the direction perpendicular to the dimers, while the “longitudinal” correlation length ξ\xi_{\parallel} is in the direction parallel to the dimers. In the disordered fluid phase, both correlation lengths are the same as expected. In the nematic phase, a level crossing of λ1\lambda_{1} occurs, and ξ\xi_{\perp} takes a smaller value than ξ\xi_{\parallel} below a certain temperature. In the columnar ordered phase, we always have ξ<ξ\xi_{\perp}<\xi_{\parallel}. In other words, the correlation length scale along the dimers become larger than in the perpendicular direction. Thus, the transverse correlation length seems to be suitable for studying the phase transition between the columnar ordered and disordered fluid phases. We also note that ξ\xi corresponds to the truncated correlation function and takes a finite value even in the ordered phase.

The entanglement entropy is defined as

SEE=iσi2lnσi2,S_{\text{EE}}=-\sum_{i}\sigma_{i}^{2}\ln\sigma_{i}^{2}, (15)

where σi\sigma_{i} denotes the singular value of the core matrix in the mixed canonical form of the uMPS. Since we calculate the horizontal and vertical uMPS with a 2×22\times 2 unit-cell structure, SEES_{\text{EE}} may depend on direction and position in the unit cell. In the disordered and nematic phases, we find that the all SEES_{\text{EE}} are equal to each other. On the other hand, in the columnar ordered phase, we find that SEES_{\text{EE}} takes on two values, depending on whether the core matrix of the horizontal uMPS is on a dimer or between dimers. The former always yields the larger SEES_{\text{EE}}. In our analysis below, we use the largest entanglement entropy thus obtained.

IV.3 Connection with coarse-grained Ashkin-Teller description

It is instructive to think in terms of a coarse-grained version ψ\psi of our local complex columnar order parameter field Ψcol\Psi_{\text{col}}, and write

ψ\displaystyle\psi \displaystyle\propto (τ1+τ2)+i(τ1τ2)\displaystyle(\tau_{1}+\tau_{2})+i(\tau_{1}-\tau_{2}) (16)

Clearly, the corresponding coarse-grained version ϕ\phi of the local nematic order parameter field Ψnem\Psi_{\text{nem}} satisfies

ϕ\displaystyle\phi \displaystyle\propto Re(ψ2)\displaystyle\text{Re}(\psi^{2}) (17)
\displaystyle\propto τ1τ2\displaystyle\tau_{1}\tau_{2}

The τ\tau defined in the above are two coarse-grained Ising fields. In the columnar ordered phase, both τ1\tau_{1} and τ2\tau_{2} are ordered; this correctly accounts for the four-fold symmetry breaking in the columnar ordered state. Nematic order corresponds to the product τ1τ2\tau_{1}\tau_{2} being ordered, without any long range order in the individual τ\tau. From the symmetries of the original problem, we see that interchanging the τ\tau is a symmetry of the theory. Thus, the natural description is in terms of a symmetric Ashkin-Teller theory with two Ising fields τ1\tau_{1} and τ2\tau_{2}.

This connection to the physics of the Ashkin-Teller model [19, 20, 21] yields a wealth of information. For instance, along a line of continuous transitions from the columnar ordered state to the disordered fluid state, we expect the critical behavior to controlled by the critical properties of the corresponding fixed line in the Ashkin-Teller model. Along this line, both the Ising fields τ1\tau_{1} and τ2\tau_{2} have a fixed anomalous dimension of η=1/4\eta=1/4 [19, 20, 21]. Since the columnar order parameter is linear in the Ising fields τ1/2\tau_{1/2}, we expect it to also scale with an anomalous exponent η=1/4\eta=1/4 all along the line of continuous transitions between columnar ordered and disordered fluid phases.

Along the fixed line of the Ashkin-Teller theory, τ1τ2\tau_{1}\tau_{2} scales with an anomalous dimension η2\eta_{2} that varies continuously [19, 20, 21] and is related to the continuously varying correlation length exponent by the Ashkin-Teller relation η2=11/2ν\eta_{2}=1-1/2\nu. Since the nematic order parameter ϕτ1τ2\phi\sim\tau_{1}\tau_{2}, we expect it to have an anomalous dimension η2\eta_{2} [7] given by this relation all along the line of continuous transitions between columnar ordered and disordered fluid phases.

In the Ashkin-Teller model, the point at which Ashkin-Teller line splits into two lines of Ising transitions is known to have the symmetries for the four-state Potts model [19, 20, 21, 25] ; in the phase between these two Ising transition lines, τ1τ2\tau_{1}\tau_{2} is ordered although τ1\tau_{1} and τ2\tau_{2} remain individually disordered . The enhanced Potts symmetry at this multicritical point implies that τ1\tau_{1}, τ2\tau_{2}, and τ1τ2\tau_{1}\tau_{2} all have the same anomalous exponent. Thus η2=η=1/4\eta_{2}=\eta=1/4 at this point, and the Ashkin-Teller relation implies ν=2/3\nu=2/3. Given the correspondence made above, this implies that the nematic order parameter is expected to have an anomalous exponent of 1/41/4 at the multicritical point at which the Ising phase boundaries of the nematic phase meet the line of continuous transitions between columnar ordered and disordered fluid phases.

From this perspective, it is clear that the value of ν\nu (or equivalently η2\eta_{2}) serves as a universal coordinate for the line of continuous transitions from the columnar ordered phase to the disordered fluid phase. At full-packing, i.e., z=0z=0, the system has a description in terms of a coarse-grained Gaussian height action for a scalar height hh, and the transition from the power-law ordered high temperature state to the low temperature state is expected to be governed by a Kosterlitz-Thouless transition at which the leading cosine nonlinearity cos(8πh)\cos(8\pi h) becomes relevant. As a result, one expects ν\nu\to\infty as z0z\to 0 along the line of continuous transitions between the columnar ordered state and the disordered fluid state. From this it is clear that the multicritical point at which the two Ising lines meet cannot be at z=0z=0, since this multicritical point corresponds to a value of ν=2/3\nu=2/3.

This theoretical perspective and the resulting expectations informs much of the data analysis we present in the next section.

V Numerical results

Before getting into the details, it is useful to provide a summary of our results for representative slices through the phase diagram, as these slices clarify the overall picture and help answer the question raised in Introduction.

V.1 Overview

To this end, we first consider a fixed z=0.2z=0.2 slice and display the computed two-dimensional phase diagram in the TTvv plane (with u=1vu=1-v). This is shown in Fig. 4.

For v0.7v\leq 0.7, there is a direct temperature driven phase transition between the columnar ordered and disordered fluid phases. As vv is increased further, this phase boundary splits slightly below v=0.8v=0.8 into two transition lines and the nematic phase appears as an intermediate phase beyond this multicritical point at which three transition lines meet. We have also checked that a corresponding slice at somewhat larger zz reduces the temperature scale of the transitions. The transition temperatures shown in Fig. 4 is determined from the peak position of the correlation length estimated by the TN method. The result of the MC method agrees with it within errors that are smaller than the symbol sizes used.

Next we consider slices with fixed v=0.9v=0.9 and v=0.8v=0.8 (with u=1vu=1-v) and display the computed two-dimensional phase diagram in the TTzz plane. This is shown in Fig. 5. The transition points are determined in the same way as Fig. 4. Since the fully packed z=0z=0 system is particularly challenging for TN computations, we do not extend our study all the way to z=0z=0. Nevertheless, we are able to go to low enough zz to demarcate the essential features of the phase diagram. It would be difficult to obtain this phase diagram using the MC method because the phase boundaries cannot be calculated with such precision due to the finite size effect.

At v=0.8v=0.8, the low-temperature nematic phase is quite narrow and disappears below the multicritical value of zz which is close to z=0.1z=0.1. On the other hand, for v=0.9v=0.9, the nematic phase is very broad and seems to exist even at very low values of zz. However, our detailed computations reveal that there is no nematic state below a multicritical threshold value of zz which is close to z=0.002z=0.002 (Fig. 5). The actual monomer densities associated with these multicritical points are extremely small: For v=0.8v=0.8, the multicritical monomer density is about δ=0.005\delta=0.005. At v=0.9v=0.9, the multicritical monomer density is a much lower value of 5×1055\times 10^{-5}.

This conclusion is contrary to that of Ref. [22]. However, it is entirely consistent with our understanding of the phase boundaries based on the coarse-grained effective field theory. Indeed, as we have already reviewed earlier, the multicritical point is expected to have rather different universal behavior from the transition at full packing since the former is expected to correspond to a η2=1/4\eta_{2}=1/4 and the latter corresponds to η2=1\eta_{2}=1 (where η2\eta_{2} is the anomalous exponent associated with the nematic order parameter). As a result, for v/u<v/u<\infty, there is no consistent scenario in which the multicritical point coincides with the transition at full packing. The resolution is of course that the multicritical value of zz approaches z=0z=0 extremely rapidly as v/uv/u is increased, but does not reach z=0z=0 at any finite v/uv/u.

In the rest of this section, we display our results for a few representative values of vv and zz, and provide a detailed account of the analysis that leads to these phase diagrams and this overall conclusion.

V.2 Detailed analysis

We use both tensor network (TN) and Monte Carlo (MC) methods to obtain the nematic and columnar order parameters, since these two complementary methods provide a nontrivial consistency check on each other. Figure 6 shows the temperature dependence of the order parameters at v=0.6v=0.6 and v=0.9v=0.9 with z=0.2z=0.2.

At v=0.6v=0.6, both the order parameters take on nonzero values below T=0.7714T=0.7714, signaling the onset of columnar order. On the other hand, at v=0.9v=0.9, we find that a nematic phase exists between T1=0.722T_{1}=0.722 and T2=0.790T_{2}=0.790 , as is clear from the fact that the columnar order parameter vanishes but the nematic order parameter takes on a nonzero value. The transition temperatures are estimated by identifying the crossing points of the Binder ratios, as shown in Fig. 7 for the Binder ratios calculated by the MC simulations at v=0.9v=0.9 and z=0.2z=0.2. These crossing points are found to be consistent with the transition temperature estimated by the TN method.

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Refer to caption
Figure 6: The square of order parameters at (a) (u,v,z)=(0.4,0.6,0.2)(u,v,z)=(0.4,0.6,0.2) and (b) (0.1,0.9,0.2)(0.1,0.9,0.2). The filled (open) symbols denote the columnar (nematic) order parameter. The statistical error is smaller than the symbol size. The results by TN with χ=128\chi=128 are also shown by the small dots connected by a line.
Refer to caption
Figure 7: The Binder ratio for columnar and nematic orders at (u,v,z)=(0.1,0.9,0.2)(u,v,z)=(0.1,0.9,0.2). The dashed vertical lines denote the critical temperature obtained by the TN method.

We obtain the scaling dimensions of various quantities at these transitions by performing a finite-size scaling (FSS) analysis, using the following FSS form for the columnar and nematic order parameters,

|ma|2L2xaf((TTc)L1/ν),\langle|m_{a}|^{2}\rangle\sim L^{2x_{a}}f\left((T-T_{c})L^{1/\nu}\right), (18)

where xax_{a} denotes the scaling dimension of the corresponding operator Ψa\Psi_{a} (a=col,nema=\text{col},\text{nem}); these scaling dimensions are related to the anomalous exponents introduced earlier via xcol=η/2x_{\text{col}}=\eta/2, xnem=η2/2x_{\text{nem}}=\eta_{2}/2. Likewise, the scaling dimension of the energy operator is related to the correlation length exponent introduced earlier: xt=21/νx_{t}=2-1/\nu.

We use the kernel method [36] to infer the critical exponents and the critical temperature and estimate their confidential intervals. At the best fit value of the scaling dimensions and the transition point, all data collapse reasonably well onto a single curve as shown in Fig. 8.

The scaling dimensions are plotted in Fig. 9. Below the multicritical point, i.e., along the line of continuous phase transitions between the columnar ordered and disordered fluid states, the scaling dimensions xnemx_{\text{nem}} and xtx_{t} are seen to continuously change with vv, while xcolx_{\text{col}} remains constant at a value consistent with the theoretical expectation of xcol=1/8x_{\text{col}}=1/8. We have checked that the corresponding exponents η2\eta_{2} and ν\nu satisfy the Ashkin-Teller relation η2=11/2ν\eta_{2}=1-1/2\nu, i.e., xt/4=xnemx_{t}/4=x_{\text{nem}} within our errors. On the other hand, we have xt/4xnemx_{t}/4\neq x_{\text{nem}} for v0.8v\geq 0.8. This discontinuous change in the critical index ratio strongly suggests the change from the single transition to the two separate transitions, i.e., the existence of the multi-critical point. The expected η=η2=1/4\eta=\eta_{2}=1/4 at the multicritical point is actually realized at about v=0.7v=0.7. Parenthetically, we note that we find a decoupled Ising point at about v=0.3v=0.3 in the z=0.2z=0.2 plane, where we have xnem=0.25x_{\text{nem}}=0.25 and xt=1.0x_{t}=1.0.

Refer to caption
Figure 8: The FSS plots at (u,v,z)=(0.4,0.6,0.2)(u,v,z)=(0.4,0.6,0.2) for (a) the columnar order parameter, (b) the nematic order parameter, (c) the columnar Binder ratio, and (d) the nematic Binder ratio.

The scaling dimension of the energy operator can also be estimated from the FSS analysis of the Binder ratio as shown in Fig. 8. Although the nonmonotonic behavior of the Binder ratio for columnar order and the relatively closely spaced successive transitions makes this difficult, we obtain almost the same results for xtx_{t} from this analysis, as we do using the earlier analysis in terms of the order parameters. We emphasize that nonmonotonicity has to do with the differing character of the columnar order parameter fluctuations in the nematic and the disordered fluid phases, and the related presence of a proximate multicritical point. Similar nonmonotonicity has been noted in the J1J_{1}-J2J_{2} Ising model earlier [37]. In contrast to other examples of such behavior in frustrated Ising models, which is associated with a proximate weakly first order transition, we do not find evidence of any first-order transitions for the values of vv studied here.

Although it is difficult to completely exclude possibility of the weakly first-order phase transition around the multicritical point in our simulations, the weight of evidence suggests that the presence of a sizable vv term replaces the first order transition found in Refs. [16, 17] by an intermediate nematic phase flanked by two second-order Ising phase boundaries. This is consistent with the fact that generalized four-state clock models, which serve as a discrete hard-spin analog of the coarse-grained description in terms of order parameter fields ψ\psi and ϕ\phi, are known for some parameter values to have such an intermediate phase flanked by two Ising lines that meet at a multicritical point with enhanced four-state Potts symmetry at the end of a line of Ashkin-Teller transitions [25].

The multicritical point at v=vc(z)v=v_{c}(z) is expected to have the four-state Potts universality. It is difficult to determine accurate location of the multicritical point because of the finite-size or finite bond-dimension effect. To make matters worse, one also expects that a logarithmic correction appears at the four-state Potts model. Our data, however, support the S4S_{4} symmetry at the multicritical point. The order parameters satisfy mnem>mcolm_{\text{nem}}>m_{\text{col}} below vcv_{c}, while mnem>mcolm_{\text{nem}}>m_{\text{col}} for v>vcv>v_{c} (Fig. 6). Thus we expect that mcolmnemm_{\text{col}}\simeq m_{\text{nem}} at v=vcv=v_{c}, which indicates the emergent S4S_{4} symmetry.

Refer to caption
Figure 9: The scaling dimensions estimated by the FSS analysis of the order parameters (18) at z=0.2z=0.2. The horizontal dashed lines indicate xh=1/8x_{h}=1/8 and xt=1x_{t}=1 in the Ising universality class. The red crosses indicate xt/4x_{t}/4, which should be equal to xnemx_{\text{nem}} on the Ashkin-Teller line.

By definition, the scaling dimension also appears in the corresponding critical two-point correlation function as Ca(r)r2xaC_{a}(r)\propto r^{-2x_{a}}. We consider the correlation function along an axis because the uMPS can easily calculate it. The correlation function between the local quantities is defined as

Ca(r)1N𝝆Ψa(𝝆)Ψa(𝝆+r𝒆α).C_{a}(r)\equiv\frac{1}{N}\sum_{\bm{\rho}}\left<\Psi_{a}(\bm{\rho})\Psi_{a}^{*}(\bm{\rho}+r\bm{e}_{\alpha})\right>. (19)

In our TN simulation, 𝝆\bm{\rho} runs over sites in the 2×22\times 2 unit cell, which corresponds to a value of N=4N=4. For correlation between monomers, the truncated correlation function,

Cmono(r)1N𝝆{nm(𝝆)nm(𝝆+r𝒆α)nm(𝝆)nm(𝝆+r𝒆α)},C_{\text{mono}}(r)\equiv\frac{1}{N}\sum_{\bm{\rho}}\bigl{\{}\left<n_{\text{m}}(\bm{\rho})n_{\text{m}}(\bm{\rho}+r\bm{e}_{\alpha})\right>\\ -\left<n_{\text{m}}(\bm{\rho})\right>\left<n_{\text{m}}(\bm{\rho}+r\bm{e}_{\alpha})\right>\bigr{\}}, (20)

is expected to scale as r2xtr^{-2x_{t}}. As shown in Fig. 10, the scaling dimensions extracted by the linear fitting of the correlation functions agree with the results obtained by the FSS analysis.

Refer to caption
Figure 10: The correlation functions at T=0.77138T=0.77138 and (u,v,z)=(0.4,0.6,0.2)(u,v,z)=(0.4,0.6,0.2) calculated by the TN method with χ=128\chi=128. The monomer-monomer truncated correlation function is shown in the inset. The dashed lines are obtained by the linear fitting.

The central charge is another important universal property of a critical point. According to the conformal field theory, the correlation length ξ\xi and the entanglement entropy SEES_{\text{EE}} are related by the Calabrese-Cardy formula at criticality:

SEE=c6lnξ+const.,S_{\text{EE}}=\frac{c}{6}\ln\xi+\text{const.}, (21)

where cc denotes the central charge.

One of the advantages of the TN method is that these two quantities can be calculated naturally. Figure 11 clearly shows that the values obtained from the TN method are consistent with the Cardy-Calabrese formula (21). Based on the theoretical framework outlined in the previous section, the continuous phase transition between the columnar ordered and disordered fluid phases is expected to have a central charge of c=1c=1. On the other hand, the continuous Ising phase boundaries of the nematic phase are expected to have a central charge of c=1/2c=1/2. From the results displayed in Fig. 11, we see that our results do indeed conform to both these expectations.

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Figure 11: The entanglement entropy SEES_{\text{EE}} vs the transverse correlation length ξ\xi_{\perp} at (a) (u,v,z)=(0.4,0.6,0.2)(u,v,z)=(0.4,0.6,0.2) and (b) (0.2,0.8,0.2)(0.2,0.8,0.2). The peaks of SEES_{\text{EE}} are shown by a large symbol. The dashed lines are guides to the eye and its slope is equal to c/6c/6 corresponding to the Calabrese-Cardy formula (21).
Refer to caption
Figure 12: (a) The eighth power of the order parameters and (b) the inverse of the correlation length at (u,v,z)=(0.1,0.9,0.2)(u,v,z)=(0.1,0.9,0.2). The linearity of them around the transition points agrees with the Ising universality class.

Above the multicritical point (v>vcv>v_{c}), there are two phase transitions, the columnar-nematic and nematic-disorder ones. Although the FSS result of xtx_{t} deviates from the expected value (Fig. 9), we believe that it is due to the correction to scaling and effects from another critical point. The TN result at v=0.9v=0.9 shows that the eighth power of the order parameters and the inverse of the correlation length are linear to the temperature near the criticality (Fig. 12). This fact strongly indicates that these critical exponents satisfy β=1/8\beta=1/8 and ν=1\nu=1, which is consistent with the Ising universality.

Finally, we comment on the approach of the multicritical point to z=0z=0 as v/uv/u is increased. This happens very rapidly, and simultaneously, the phase boundary between the columnar and nematic phases, shown by orange squares in Fig. 5, approaches the vertical temperature axis as v/uv/u increases. This is clear from monitoring the relative values of mcolm_{\text{col}} and mnemm_{\text{nem}} as in our earlier discussion about the symmetry of the multicritical point. Eventually, in the limit v/uv/u\rightarrow\infty, the columnar phase vanishes and only the phase boundary between the nematic and disordered phases remains.

VI Discussions and Summary

In this paper, we have studied the classical grand-canonical monomer-dimer model on the square lattice with two types of attractive interactions. We have determined the phase diagrams and analyzed the nature of the phase transitions using MC and TN methods. The phase transition between disordered and columnar ordered phases shows the same feature as the Ashkin-Teller transition, where the critical exponents change continuously. On the other hand, both nematic-disordered and columnar-nematic phase transitions belong to the Ising universality class. Our numerical results show that the multicritical point, where three phases meet, has a positive fugacity when v/u<v/u<\infty.

Our conclusions and the theoretical framework within which they are situated has already been discussed at length. Here, we confine ourselves to highlighting one aspect of the phase diagram that appears to be worth further study. This has to do with the rapidity with which the multicritical point (at which the two Ising transitions meet the Ashkin-Teller line) moves towards z=0z=0 as we increase v/uv/u. The proximity to the full-packing limit raises the possibility that aspects of this could be understood by expanding about the full-packing limit in some way. It would be interesting to explore this in future work. A related question has to do with the extent of the nematic phase itself in the TTzz phase diagram at large v/uv/u. As noted in Ref. [22], one expects that the low-temperature phase at full-packing will be columnar ordered for any finite value of v/uv/u, no matter how large. However, the extent of this phase in zz decreases very rapidly with increasing v/uv/u, until, at asymptotically large values of v/uv/u, the columnar state only exists at full packing. Again, it would be interesting if some small zz expansion method could yield a more quantitative characterization of this phenomenon, which is very challenging to study by numerical methods.

Acknowledgements.
The work of S.M., H.-Y.L., and N.K. was supported by JSPS KAKENHI Grants No. JP19H01809 and No. JP20K03780. K.D. was supported at the Tata Institute of Fundamental Research by DAE, India and in part by a J. C. Bose Fellowship (JCB/2020/000047) of SERB, DST India, and by the Infosys-Chandrasekharan Random Geometry Center (TIFR). The inception of this work was made possible by a Visiting Professor appointment (K.D.) and associated research support at the Institute for Solid State Physics (ISSP), the University of Tokyo. The computational component of this work has been done using the facilities of the Supercomputer Center, ISSP.

References