Dark states in an integrable central spin model
Abstract
Eigenstates of central spin models in which the central spin is unentangled with the environment are known as dark states. They have recently been observed in a class of integrable models. Here we find that dark states are present in models, but only for particular configurations of the central spin magnetic field. We show this via an explicit construction of the Bethe states.
1 Introduction
Central spin models have gained renewed attention due to their possible applications in modern quantum technologies focused on quantum sensing and metrology [16]. This is due to their integrability allowing high-fidelity control of these systems at a mesoscopic scale, where the exponentially increasing size of the Hilbert space would in general be prohibitive [6]. The central spin allows the dynamics of the spin bath to be monitored, and for feedback to be used to steer the dynamics of the bath in a desired direction. There are several physical or engineered systems for which central spin models provide a theoretical model. These include nitrogen vacancy (NV) centres in diamonds [23], room temperature quantum memory storage [18, 21, 22], quantum batteries [11] and quantum dots [2, 19] – an active area of research which gained public attention through the 2023 Nobel prize for Chemistry [13].
On the theoretical side, these models have been known for their integrability since Gaudin’s seminal paper [8]. Integrability allows for the analytic solution of the eigenstates and eigenspectrum of the models through the Bethe Ansatz. This makes these models well suited for studies of their equilibrium and dynamical behaviour; in particular, tests of the Eigenstate Thermalisation Hypothesis (ETH) and investigation of many-body localisation [1, 12, 17, 22]. Integrability is also essential for perturbative solutions of physical models. For example, integrability provides a wavefunction Ansatz in variational eigensolvers to model strong electron correlation in quantum chemistry [7].
Integrability is also of great interest in mathematical physics. There is ongoing work on extending or modifying known integrable models to obtain new ones. This has recently led to establishing that the model, which models certain resonant dipolar spin systems, is integrable [5, 21]. Integrability was subsequently extended to the model [20] using conserved charges discussed in [14], and the same charges with self-interaction obtained by Skrypnyk [15]. These charges were diagonalised using several modifications of the standard algebraic Bethe Ansatz for arbitrary spin [15]. These expressions for the eigenvalues can also be obtained through the use of functional relations as described in [20].
Here we derive the central spin model Hamiltonian and its charges through a limit of the charges for the Gaudin model in [15]. We also derive a second integrable class of central spin models, which are seen to simply be a different parametrisation of the original model. With this reparametrisation we obtain regularised eigenvalue and eigenstate results for the central spin model. We show that these reproduce the diagonalisation results in the literature [3, 21] in the appropriate limits. It is found that dark states, states in which the central spin is not entangled with the environment, are present for special configurations of the magnetic field . This is reminiscent of the model for which these occur for an out-of-plane magnetic field, [5, 21].
In Sect. 2 we derive two examples of central spin Hamiltonians and their conserved charges for spin- central spin. We then show how these are different parametrisations of the same integrable model. After performing a reparametrisation which regularises the eigenstate results of [15], we find the eigenstates for the central spin model in Sect. 3. We show that for special magnetic field configurations dark states occur, in analogy to those that were seen in the out-of-plane model [21]. Concluding remarks are given in Sect. 4. In the Appendix 5 we take the isotropic limit to confirm that these recover the results for the model. This is supplemented with some heuristic arguments and numerical results about how the dark states emerge from the states with generic magnetic field configurations.
2 Derivation of integrable central spin Hamiltonians
Consider a set of spin operators satisfying the standard canonical commutation relations
(1) |
where and is the Levi-Civita symbol. Introduce a set of distinct parameters with and such that for all . Also define .
Integrable central spin models, with spin-1/2 central spin and arbitrary bath spins, are derived from the following conserved charges 111We use instead of to prevent confusion with of the Hamiltonian, Eq. (7) below.
(2) | |||
To do this, we take to be the spin- operators, identify the zero subscript with the central spin and the other subscripts with the bath spins. The zeroth charge will then become the central spin Hamiltonian and , its conserved charges. Noting that for spin-1/2 operators we have
it is convenient for the zeroth charge to subtract off the squared spin operator terms. After making the change of variables for the magnetic field, we obtain the first class of XY central spin models through the limit as with the Hamiltonian being
(3) | |||||
and the charges
(4) | |||||
reproducing those introduced in [20].
For the second class of Hamiltonians we use the variables for the magnetic field and instead of , letting . We make a change of variables for the magnetic field, . Taking the limit as leads to the Hamiltonian
(5) | |||||
and the charges
(6) | |||||
where the last equality is obtained through a shift by . Note that for this class the limit as is an model (after making the transformation ) in contrast to the first class.
These two classes can be seen as different parametrisations of the parameters and the magnetic field components. The integrable central spin Hamiltonian
(7) |
was seen in [20] to be characterised by , with the constant being free to be chosen through rescalings of the parameters and magnetic field components. The isotropic case where corresponds to the model, as seen for example in [21]. In the above two cases is seen to be respectively and . The reparametrisation relating the two classes is
Specifically, the charges (2) in the variables and , under this reparametrisation take the form (after making the rotation and adding )
(8) | |||||
where
with the redefined magnetic field components
Henceforth we will only consider the parametrisation given in the first class and take . However, we will see that the second parametrisation will be useful for obtaining the eigenstates of the model.
3 The eigenstates
The eigenstates of the charges , as well as their eigenvalues, have been found in [15]. Here we recall the algebraic setup and the results required in order to obtain the eigenstates and eigenvalues of and its conserved charges .
3.1 Relations for the Algebraic Bethe Ansatz
Introduce the Lax algebra generators (respectively corresponding to , and in [15]) 222Again using to prevent confusion with of the model.
where and the operators satisfy the commutation relations
The Lax algebra generators satisfy the relations
(9) |
We also define operators shifted by a constant term, necessary to build the appropriate Bethe states,
and with these define
(10) |
Now in order to describe the eigenstates of the charges we use the following representation of the operators
Following the notation of [15] we also introduce the reference states defined as
(11) |
where the are respectively lowest and highest weight states satisfying
for half non-negative integers , i.e. . For the spin labelled by the 0 subscript, for which , we use the following notational convention
For conciseness we will also use the notation
when identifying spins 1 to as bath spins.
3.1.1 Reparametrised operators.
3.2 Eigenstates of
To fully capture the possible types of eigenstates of the central spin model we first give the construction of the states via the supersymmetry of the model, before obtaining the states for generic magnetic field configurations from the limits of Sect. 2.
3.2.1 Construction from supersymmetry.
Define the spin raising and lowering operators , and supercharges , where
(13) |
The supercharges satisfy and . Recall from [20] that the Hamiltonian (3) can be written as
(14) |
With this one sees that is related to a supersymmetric Hamiltonian through
Rewriting this in the eigenbasis of
shows that can be diagonalised with eigenstates of the form
where the subscript denotes a central spin state and a bath-spin state. Observe that the the states are respectively eigenstates of the charges . Due to the supersymmetry, the eigenstates of are either singlets or doublets. The singlets ,
are also eigenstates of . Whereas for the doublets ,
we can diagonalise to obtain the eigenstates
where .
From the above construction it is clear that we can obtain the eigenstates of the model from those of or equivalently, due to simultaneous diagonalisability, respectively from . To do so we observe that with the inverted reparametrisation introduced in Sect. 2
we have expressions in terms of the Lax algebra generators as
noting that .
3.2.2 Dark states.
Here we will demonstrate how dark states can be identified from the Bethe state construction. Assuming the roots are distinct and not equal to we find using the algebraic relations (3.1)
Noting that
where
we see that the Bethe state will be an eigenstate with zero eigenvalue if 333See Sect. 5.1 of the Appendix for the full argument that these are the only magnetic field configurations admitting dark states.
and the “unwanted terms” vanish. This corresponds to the roots satisfying
where are the eigenvalues of for the reference states .
Due to these being zero eigenvalue states of , they correspond to the singlet states. Hence, making the reparametrisation (12), the states
are eigenstates of with energy if the roots satisfy the Bethe Ansatz equations
and the magnetic field components satisfy
(17) |
3.2.3 Bright states
Due to we see that the doublets are Bethe states with one of the roots equal to . In this case one finds that
where
We again see that this will be an eigenstate, with eigenvalue
if
and the roots satisfy
Hence, making the reparametrisation (12), the states
(18) |
are eigenstates of with energy
if the roots satisfy the Bethe Ansatz equations
and the magnetic field components satisfy
These states (18) are referred to as bright states [21] due to the central spin being entangled with the bath, in contrast to the dark states.
Before we conclude this section, we note that in the reparametrisation
(19) |
i.e. a root equal to corresponds to a root divergent in the reparametrisation.
3.2.4 Generic eigenstates of the charges .
To describe the eigenstates of the model for generic magnetic field configurations we will use the corresponding results of [15] for the charges .
As was shown in [15], the charges
have the eigenstates constructed respectively from lowering or raising operators
(20) |
with respective eigenvalues
(21) | |||||
The Bethe roots , with , are the solutions to the set of Bethe equations
(22) |
As we will mainly be working with the variables of the reparametrisation (12), using also the notation of Sect. 3.1.1, we also give their corresponding expressions. Here the Bethe roots satisfy the modified Bethe equations
(23) |
while the eigenvalues of the charges , using the result of (8), are
(24) | |||||
Before moving onto the eigenstates of the central spin model, we note that for generic model parameters the states constructed by either applying the lowering operators to the highest weight state , or the raising operators to the lowest weight state , constitute a complete set of eigenstates. This follows from quadratic identities of the charges similar to those seen in [20], and extended to the eigenvalues. From these the Bethe Ansatz equations are seen to be the consistency equations for the parametrisation in terms of the roots . Completeness is then argued similarly as in [9, 10] by assuming regularisability and the one-dimensionality of the simultaneous eigenspace for generic parameters. We also observe that there is a map between the states obtained via the raising and lowering operators through the symmetry of the charges, .
3.3 Generic eigenstates of the model
We now proceed to obtain the eigenstates of the model with the limits defined in Sect. 2. Recall from (3) that we obtain the Hamiltonian by taking the limit of as after applying a rescaling and a constant shift. Hence the eigenstates are found from the eigenstates of the charge in the above limit. As we saw in Sect. 3.2.3, the Bethe roots can diverge, so we analyse the behaviour as two cases.
Finite roots in the limit.
Assuming the roots stay finite in the limit, the raising operators become
Hence the eigenstates are dark states
However, from Sect. 3.2.2 we saw that these will in general only occur when (17) holds. So in this case the Bethe Ansatz would have to be modified to that seen in the same section. We also remark that the dark states can be seen to come from entangled states in the limit as the magnetic field configuration satisfy (17).444See also Sect. 5.2.1 in the Appendix for a heuristic discussion of this.
One of the roots diverges.
Assuming that we have
where
The eigenstates become
using the expressions (13) for in the last line. Here the roots satisfy
and satisfies
The energy is
(26) |
and the eigenvalues of the charges are
Due to the quadratic equation for this gives two sets of eigenstates with different energy. However, recalling the completeness argument of Sect. 3.2.4, the states with the same energy are the same. So a state constructed from lowering operators with corresponds to a state constructed with raising operators with (and vice-versa a “raised” state with corresponds to a “lowered” state with ).
We note that, since these are the eigenstates of the charges , projecting onto for the central spin, the bath states
are eigenstates of the charges with . We see that this is consistent with the Bethe Ansatz equations. To see that the eigenstates are also consistent with the construction via supersymmetry we rewrite them as
(27) |
using expression (26) for the energy. Then by (19) we observe that
Whereas, we see from (3.2.1) that
is an eigenstate of with eigenvalue , so by the previous relation
Hence we find that
which matches (3.2.1).
4 Conclusion
We have derived the central spin model Hamiltonian , (7), and charges given in [20] as a limit of the model charges with self-interaction obtained by Skrypnyk [15]. This allowed the diagonalisation results found in [15] for the charges via a modified Algebraic Bethe Ansatz to be used to diagonalise . However, in order for these results to connect with those found for the model we regularised the charges via a reparametrisation. Lastly, we showed that the dark states of the model without an in-plane magnetic field [5, 21] can be seen as a special case of dark states of the model for special configurations of the magnetic field.
These results open the way for finding form factors and correlation functions for the central spin model as well as probing the dynamics for large systems. The characterisation of the magnetic field configurations supporting dark states and their emergence via special limits of the parameter can provide experimental criteria for preparing these states with high-fidelity and determining how far a bright state is from being a product state.
Another extension of this work would be to the case of a spin-1 central spin. Here it has been shown that the central spin model is integrable for an out-of-plane magnetic field [17] and more recently for an arbitrarily oriented magnetic field [4]. Integrability for the model can also be shown through a minor modification of the charges found in [4]. In the latter work it was numerically demonstrated that dark states can emerge at asymptotically large coupling, just as seen in the central spin-1/2 model for an arbitrarily oriented magnetic field [5]. This raises the possibility of the existence of these states for certain special magnetic field configurations of the and spin-1 central spin models. However, determining whether these dark states actually exist is complicated by the fact that the relationship between the model and the known class of Richardson-Gaudin models is not yet understood.
5 Appendix
5.1 Characterisation of magnetic field configurations admitting dark states
In this section we supplement Subsect. 3.2.1 – to argue that the eigenstates given by the singlet states are the only dark states, i.e. product states of the central spin and bath spins – and Subsec. 3.2.2, to characterise when they occur.
Firstly, with regards to the singlets we note that for the eigenstates
to be dark states requires If we assume that neither of these is zero this implies that are eigenstates of both charges since are respectively eigenstates of the charges due to
Hence they are also eigenstates of for all . This determines and would lead to a contradiction if we took e.g. since this holds for all . This also means that dark states can only occur if or in which case the central spin state is respectively . Furthermore note that by the supersymmetry this means (as these are originally doublets) that is a singlet.
Next we will show that these dark states only occur when
(28) |
where and . Define , so that we can write the local operators of in terms of as
If we now define operators
then it can be checked that these respectively satisfy the relations
Noting that
we can respectively diagonalise with the eigenvectors
where the highest weight vector is defined as
to find that it has respective eigenvalues
We see that these are zero (i.e. the corresponding states are dark states) when (28) holds.
For the following section we briefly mention the model case. Here the dark states are zero eigenvalue eigenstates of
From this we see that is strictly upper or lower triangular if and only if , and so dark states can only occur if .
5.2 Eigenstates of the central spin model
Due to the reparametrised expressions for the eigenstates and eigenvalues of the Gaudin model charges all being non-singular in the limit , we can rederive the diagonalisation results for the model. This will also give us an idea of how the dark states emerge in the limit of the special magnetic field configurations of Subsect. 3.2.2.
Taking the limit as , the eigenstates of the charges
become
with . Here
and the reference states now satisfy
or in other words
The Bethe roots in turn now satisfy
(29) | |||||
with , while the eigenvalues of the charges are
To obtain the eigenstates of the central spin model we can simply use the results for the model in the limit . For a magnetic field with a non-zero in-plane component the eigenstates are entangled states of the central spin and bath, the bright states of [21], taking the form
with the roots satisfying the Bethe Ansatz equations
and the equation for coming from the Bethe Ansatz equation for ,
(30) |
The energy is
while the eigenvalues of the charges are
Observe here that if is a solution to the first equation of then is a solution to the second (respectively, if is a solution to the second equation of then is a solution to the first equation), due to the Bethe equations for the roots being the same for both. These have identical energy and charge eigenvalues. Therefore, based on the argument of the correspondence between eigenstates constructed using raising or lowering operators, they are proportional to the same eigenstate. We note these expressions match those of [3] and [21], where in the former and in the latter .
5.2.1 Recovering the dark states for .
As argued in Sect. 5.1, in the case of a non-zero in-plane magnetic field, , there are no dark states. We find numerically (see also Sect. 5.3) that the dark states of the model with no in-plane field are recovered in the limit as via or for some of the eigenstates. For simplicity we will only discuss the case where for all the bath spins .
In the case where , the states become
where, from (29), the roots satisfy
with due to some of the roots becoming zero and their corresponding raising and lowering operators being asymptotically . This follows by noting that the Bethe states will become eigenstates of the total operator, as the raising and lowering operators are proportional to products of total spin raising or lowering operators in the zero in-plane field limit, and since the model in this limit has a global symmetry.
Using the correspondence coming from the symmetry of the charges, , this can be written as
with the roots satisfying
Note that the bath component of the state now satisfies (see for example [21])
giving the dark state
As explained in Sect. 5.2, the states with constructed with lowering operators correspond to states with constructed with raising operators (and vice versa for and ). So the states constructed with raising operators for which are the same dark states as those constructed with lowering operators with the behaviour (and vice versa for and ) that we just found. However, for completeness we will sketch here the behaviour in this limit. For conciseness let so that the state asymptotically becomes
where again some of the roots go to zero. Expanding this out, the state has the form (for )
where
For a dark state with roots, all the for are zero while
The state in the limit then becomes equal to the dark state
with and where the roots satisfy
5.3 Emergence of dark states
In the following we show numerical examples of dark states emerging due to when condition (28) is met. We set the model parameters as , 555This was generated in Mathematica with SeedRandom 1324 using RandomReal in the range 0.4 to 1.3.
and only look at the case where all spins are . Then for different we change so that we approach conditions where dark states emerge. As we use states constructed from with the lowering operators , we should observe for dark states that . We label states by the eigenvalue of .
5.3.1 Dark states for .
In this case there are only two dark states in the limit, both with the same eigenvalues for the charges but with different energies.
5.3.2 Dark states for .
In this case there are six dark states in the limit.
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