Dynamic characteristics of terahertz hot-electron graphene FET bolometers: effect of electron cooling in channel and at side contacts
Abstract
We analyze the operation of the hot-electron FET bolometers with the graphene channels (GCs) and the gate barrier layers (BLs). Such bolometers use the thermionic emission of the hot electrons heated by incident modulated THz radiation. The hot electron transfer from the GC into the metal gate. As the THz detectors, these bolometers can operate at room temperature. We show that the response and ultimate modulation frequency of the GC-FET bolometers are determined by the efficiency of the hot-electron energy transfer to the lattice and the GC side contacts due to the 2DEG lateral thermal conductance. The dependences of these mechanisms on the band structure and geometrical parameters open the way for the GC-FET bolometers optimization, in particular, for the enhancement of the maximum modulation frequency.
I Introduction
The specific band alignment in metal/black-PxAs1-x layer/graphene structures [1, 2] enables an enhanced thermionic electron and hole thermionic emission between the graphene and metal layers. Since the absorption of THz leads to an effective electron (holes) heating, the field-effect transistors (FETs) based on such structures with the metal gate (MG), b-PxAs1-xbarrier layer (BL), and graphene channel (GC) can be used as sensitive bolometric detectors [3, 4, 5]. The responsivity of the GC-FET bolometers is determined by the rate of the carrier cooling due to the transfer of their energy to the GC and the side contacts (source and drain) as well as the thermionic emission [4, 5, 6, 7] (the Peltier cooling). On the other hand, the same processes determine the speed of the bolometric detectors in question. The roles of the effects in question depend on the structural parameters and the temperature. The plasmonic resonances in the gate GC of the devices under consideration can substantially affect the absorption of the impinging radiation and, hence, the detector performance. The recently proposed GC-FET bolometers with the composite BL [8, 9] have reinforced plasmonic resonances. Such a composite BL is made of the h-BN layer with a short narrow-gap black-PxAs1-x region. The latter serves as the electron emission window, through which the hot electrons pass from the GC into the MG. Since the quality of the h-BN/GC interface supports very high electron mobility (see, for example, [10, 11]) and, therefore, a low electron collision frequency, the plasmonic oscillations damping in the GC-FETs can be markedly weaker than in the GC-FETs with black-PxAs1-x BLs. Due to a relatively narrow emission window, the role of the Peltier cooling is diminished.
In this paper, we consider the GC-FETs with the n-type GC and composite h-BN/b-P BL and analyze the dynamics of the two-dimensional electron gas (2DEG) heating. We calculate the GC-FET bolometer’s modulation characteristics and the ultimate modulation frequency of the detected incoming radiation signals as functions of the device structure parameters and the temperature.
II GC-FET detector structure and main model equations
Figure 1(a) schematically shows the cross-section of the GC-FET structure under consideration. The GC-FET structure incorporates the GC separated from the MC by the composite h-BN/b-P/h-BN gate BL. For the GC-FETs with the Al MG, one can set for the differences between the bottom of the BL conduction band and the Dirac point in the GC meV, and the difference in the electron affinities of the Al MG and b-P in the central section of the gate BL meV [12, 13, 14, 15, 16, 17, 18]. We assume that the electron Fermi energy in the GC is chosen to satisfy the conditions: . The lengths of the b-P central section and each the h-BN side sections are and , respectively [, see Fig. 1(a)]. Here and are the length of the GC and the length of the central GC section covered by the b-P section of the gate BL. Figs. 1(b) and 1(c) show the GC-FET band diagrams at the gate voltage for different GC sections: in the side regions () and the central region (). The current between the GC and MG in the side sections () is blocked because of the high-energy h-BN barrier. Since the energy barrier, , for electrons in the GC in the section covered by the b-P is smaller than in the sections with the h-BN gate BL, this section plays the role of the electron emission window. The band diagram shown in Figs. 1(c) corresponds to the band parameter assumed above. For these conditions, the thermionic current from the GC into the MC is associated with the electrons heated by the absorbed THz radiation in the whole GC flowing over the barrier via the central region.
The bias DC gate voltage and the signal ac voltage, are applied between the MG and the GC edge contacts. The signal voltage is produced by the energy flux, , of the impinging amplitude-modulated THz radiation (received by an antenna). Here is the THz radiation carrier frequency, and are the modulation depth and frequency (). The absorption of the received amplitude-modulated THz radiation by the 2DEG leads to transient heating. As a result, the electron effective temperature averaged over the period of the carrier signal (i.e., over the fast oscillations) is , where is the lattice temperature, is the temperature variation associated with the heating caused by the carrier signal, and is the slowly varying component associated with the modulation. The symbol denotes the averaging over the fast oscillations with the characteristic period ). The rectified DC and modulation components of the thermionic current via the b-P section, , can be presented as:
(1) |
(2) |
Here is the maximal value of the current density from the GC, (the axis is directed in the GC plane from one side contact to the other), is the GC width (in the in-plane -direction) and
(3) |
The exponential factor in the right-hand side of Eq. (3) has the activation energy for the electrons leaving the GC equal to . The maximal current density is estimated as , where and are the electron density in the GC (both associated with the doping and the gate bias voltage), the escape time of the electrons with the energy exceeding the barrier height, respectively, and is the electron charge.. Since the escape of an electron from the GC is associated with a significant change in its momentum, we set , where is the electron scattering frequency (inverse momentum relaxation time) in 2DEG at room temperature and is a phenomenological parameter (which for the virtually isotropic scattering of the electrons with the energy on acoustic phonons, can be roughly estimated as ).
In the GC-FETs under consideration, the thermionic current of the heated electrons passes via the b-P region. Considering this, Eqs. (1) and (2) can be transformed to
(4) |
(5) |
The slow variations averaged over the fast oscillations (varying with the characteristic time ) of the local electron temperature, , are governed by the following electron heat transport equation:
(6) |
(7) |
Here and are thermal conductivity and the electron thermal capacitance in the GC, and are the electron energy relaxation time and the try-to-escape time for the electrons emitted via the BL central part, respectively, cm/s is the characteristic electron velocity in GCs, is the electron scattering frequency, and , where is the 2DEG Drude conductivity, and is the ac electric field component in the GC corresponding to the modulated incoming THz radiation. The terms on the left sides of Eqs. (6) and (7), proportional to and , describe the electron energy transfer to the side contacts due to the electron heat transport along the GC and to the phonon system (particularly to optical phonons). The contribution of the Peltier cooling is disregarded because of the small emission window (. The term on the right-hand side of these equations describes the local power received by the 2DEG in the GC from the incident THz radiation (per an electron). Using the general formula for the degenerate 2DEG electron thermal capacitance [19, 20] and the expression for the GC density of states, one can obtain . The quantity , which is in line with the Wiedemann-Franz relation [21, 22].
Assuming low thermal resistance of the side contacts, the boundary conditions for Eq. (3) are set to be
(8) |
Accounting for the transformation of the THz signal receiving by an antenna to the AC electric field in the GC under the condition of the plasmonic oscillations excitation, one can obtain the following [3, 5, 9] (see, also Refs. [23,24]):
(9) |
(10) |
Here is the antenna gain (for a half-wavelength dipole antenna), is the speed of light in vacuum, and are the effective wavenumber and the plasmonic frequency, respectively, with and being the dielectric constant of the BL and its thickness.
Combining Eqs. (6), (7), (9), and (10), we arrive at
(11) |
(12) |
where and is the phase shift. Here we have accounted for the fine structure constant .
III Output rectified dc and modulation currents

(a) m, THz, ps-1, and ps, (b) m, THz, ps-1, and ps,
(c) m, THz, ps-1, (d) m, THz, ps-1, and ps.
In the most interesting frequency range , the right-hand sides of Eqs. (11) and (12) can be somewhat simplified. This allows to obtain relatively simple and transparent expressions for and in closed analytic form. Such an approach was verified by the comparison of the results of the analytical and computer modeling. As shown in Sec. IV, the results of the analytical and computer calculations are very close when .
Considering this and solving simplified versions of Eqs. (11) and (12) with the boundary conditions given by Eq. (8), at , we obtain the following formulas used for the derivation of GC-FET characteristics:
(13) |
(14) |
Here
(15) |
(16) |
where the parameters , with , and characterizing the 2DEG cooling at the side contacts,
(17) |
is the factor describing the plasmonic resonances, and is a phase shift. The factor in the right-hand sides of Eqs. (13) and (14) appears because the 2DEG conductivity and density are and , respectively, so that . One needs to note that the Fermi energy is assumed to be fixed to provide a proper band alignment as stated above.
Further, for the rectified dc current , the amplitude of the modulated current , and for the pertinent current responsivities and we obtain using Eqs. (4), (5), (13), and (14):
(18) |
(19) |
Accordingly, for the voltage responsivities we obtain
(20) |
where is the load resistance (in the GC/MG circuit).
Figure 2 shows the modulated current responsivity (amplitude of modulated current ) versus the signal frequency and modulation frequencies, and , calculated using Eq. (19).
In this and the following figures we assume that nm, , meV (to fit the condition , where for Al MG meV and meV), ps, ps-1, and meV, so that ( GHz). The chosen values of generally correspond to the electron energy relaxation in GCs primarily on optical phonons [25, 26, 27, 28, 29]. As seen in Fig. 2, the amplitude of the modulated current exhibits maxima associated with the fundamental plasmonic resonances . When the signal frequency tends to zero, the modulation current (as well as ) also approaches zero. This is because of the heating electric field along the GC vanishes in line with Eqs. (9) and (10). According to the plots in Fig. 2, the position of resonant peak shifts with changing GC length according to [compare Figs. 2(a) and 2(b)]. Comparing Figs. 2(c) and 2(d), one can see that the variation of the electron energy relaxation time leads first to higher values of at low modulation frequencies and to a faster decrease in at higher . A lowering of the resonant maxima with rising modulation frequency is attributed to the weakening of the 2DEG heating when increases
Figures. 3 and 4 show the dependencies of the modulated current peak values on the electron collision frequency (at fixed electron energy relaxation time ) and on (at fixed ) calculated for different GC length . To maintain THz for different , the curves of Figs. 3 and 4 correspond to different values of the BL thickness ().


IV Modulation characteristic
Introducing the detector modulation efficiency
(21) |
and accounting for Eqs. (18) and (19), for the fundamental plasmonic resonance () we obtain
(22) |
i.e., accounting for Eqs. (15) - (17),
(23) |
Figure 5 shows the modulation efficiency versus modulation frequency for detectors with different GC lengths and different values of scattering frequency in the main part of the CC (i.e., covered by the h-BN) at the plasmonic resonance . The dashed lines correspond to the first factor in the right-hand sides of Eqs. (22) and (23) . This factor describes the net efficiency roll-off with increasing modulation frequency associated solely with the 2DES cooling due to the electron energy relaxation in the GC. The inset on Figs. 5 shows the dependence of the second factor in Eqs. (22) and (23), i.e., on and . The factor reflects the effect of the 2DEG cooling due to the electron heat transfer to the side contacts with the absorption of the electron’s excessive thermal energy by these contacts (the heat transfer factor). As seen from Fig. 5, the modulation efficiency is markedly larger than (compare the solid and dashed lines). This is attributed to the fact that is larger than unity as shown in the inset. In the latter case the maximal modulation frequency defined by the relation exceeds .
Figures. 6 and 7 show the maximal modulation frequency . The red curves in Figs. 6 and 7 correspond to the same set of parameters.
As follows from Figs. 5 - 7, the maximal modulation frequency in the GC-FET detectors with the GC length m can be about dozens GHz.



V Comparison of modulation characteristics of GC-FETs with composite and uniform BLs
The characteristics of GC-FETs with the uniform BL can be obtained from Eqs. (1), (2), (11), and (12) setting . In this case, the electron collision frequency and the factors and should be replaced by , , and , respectively. The electron collision frequency in the GC encapsulated in h-BN is usually smaller than that in the case of the GC sandwiched between the h-BN substrate and the b-P BL [30]. The consideration of the intermediate case leads to rather cumbersome formulas and, therefore, will not be studied below.
Comparing the modulated current responsivities, and , and the modulation efficiencies, and , of the GC-FET bolometric detectors with that of the composite h-BN/b-P BL given by Eqs. (19) and (23) and those of the detectors with the uniform b-P BL (which are derived using [9]) at the plasmonic resonance, we obtain
(24) |
and
(25) |
respectively. Here , , hence providing that the GCs of devices of both types have the same length and the electron energy relaxation time , but different electron scattering frequencies and .
If the load resistance is chosen to be equal to the GC/MG resistance, i.e., inversely proportion to ,
(26) |
The latter ratio is independent of .
Figs. 8 and 9 show the results of the comparison of the voltage responsivities of the GC-FET detectors with the composite h-BN/b-P/h-BN gate BL and with the uniform b-P gate BL. One can see that the responsivity of the former exceeds that of the latter when , which corresponds to the reality. This confirms the advantage of using the composite gate BL in the GC-FET bolometric detectors under consideration.


VI Comparison of computer and analytical modeling: verification of analytical model


To verify the accuracy of the analytical results we compare the values of the normalized electron temperatures, and , obtained from the differential Eq. (11) and using the analytical formula. These values are defined as
As a result, we arrive at the following dimensionless equations, respectively:
(27) |
(28) |
Here , so that the boundary conditions are , and the factor given by Eq (17).
All equations in this work were numerically calculated with MATLAB (version 9.14.0 R2023a, Natick, Massachusetts: The MathWorks Inc.). Finding the maximal modulation frequency (Figs. 6 and 7), we used the Parallel Computing Toolbox (parfor) to speed up massive calculations. The differential Eq. (27) was solved with a standard MATLAB function dsolve.
Figure 10 shows that at low ratios of (), the computer and analytical calculations provide practically distinguishable dependences. However, at a relatively large values of (of ), the distinction is visible reaching about 15. This is confirmed also by the plots in Fig. 11.
Similar conclusion can be made in respect of the results following from Eqs. (12) and (14) (with the substitution of parameter by ).
Thus, the above comparison of the results of the computer and analytical models justifies using Eqs. (13) and (14), which provide the GC-FET characteristics with sufficiently high accuracy.
VII Comments
The GC-FET detectors with a larger exhibit smaller modulation currents (see Figs. 3 and 4). This is because at the same intensity of the impinging radiation, the amplitude of the signal electric field in the GC decreases with increasing resulting in a weaker electron heating. As seen from Eqs. (15) and (16), . However, an increase in leads to a diminishing of the electron energy transfer to the side contact. The trade-off of such factors, gives rise to a relatively weak dependence of the modulation current of the GC length. This, in particular, follows from the comparison of at m and m shown in Figs. 3 and 4.
Above, calculating the GC-FET characteristics, we assumed the room temperature operation. Lowering the working temperature might lead to a marked change of the GC-FETs performance as bolometric detectors. At lower the lattice temperatures , , and decrease, while simultaneously becomes larger. In particular, at not too low temperatures, the electron energy relaxation time and the electron scattering frequency are determined by optical phonons [27, 28] and acoustic phonons [31, 32], respectively, with and . Here meV is the optical phonon energy. This implies that the characteristics obtained above might be substantially modified for GC-FET detectors operating at low temperatures. The latter is beyond the scope of this paper and requires a separate study.
VIII Conclusion
We evaluated the performance of the hot-electron GC-FET bolometers with graphene channel and the composite h-BN/b-P/h-BN gate BL and showed that these bolometers can exhibit high values of the responsivity to the THz radiation modulated by signals of dozens GHz at room temperature. The predicted high performance of the GC-bolometers might encourage the fabrication of these devices and their characterization.
References
- [1] Y. Cai, G. Zhang, and Y. W. Zhang, "Layer-dependent band alignment and work function of few-layer phosphorene," Sci. Rep., vol. 4, 6677, Oct. 20, 2014.
- [2] X. Ling, H. Wang, S. Huang, F. Xia, and M. S. Dresselhaus, "The renaissance of black phosphorus," PNAS, vol. 112, no. 15, pp. 4523–4530, 2015.
- [3] V. Ryzhii, C. Tang, T. Otsuji, M. Ryzhii, V. Mitin, and M. S. Shur, "Resonant plasmonic detection of terahertz radiation in field-effect transistors with the graphene channel and the black-AsxP1-x gate layer," Sci. Rep., vol. 13, no. 1, 2023.
- [4] V. Ryzhii, C. Tang, T. Otsuji, M. Ryzhii, V. Mitin, and M. S. Shur, "Effect of electron thermal conductivity on resonant plasmonic detection in terahertz hot-electron bolometers based on metal/black-AsP/graphene FETs," Phys. Rev. Appl., vol. 19, no. 6, 064033, 2023.
- [5] V. Ryzhii, C. Tang, T. Otsuji, M. Ryzhii, V. Mitin, and M. S. Shur, "Hot-electron resonant terahertz bolometric detection in the graphene/black-AsP field-effect transistors with a floating gate," J. Appl. Phys., vol. 133, no. 17, 174501, 2023.
- [6] J. F. Rodriguez-Nieva, M. S. Dresselhaus, and L. S. Levitov, "Thermionic emission and negative / in photoactive graphene heterostructures," Nano Lett., vol. 15, no. 3, pp. 1451–1456, 2015.
- [7] J. F. Rodriguez-Nieva, M. S. Dresselhaus, and J. C. Song, "Enhanced thermionic-dominated photoresponse in graphene Schottky junctions," Nano Lett., vol. 16, no. 10, pp. 6036–6041, 2016.
- [8] M. Ryzhii, V. Ryzhii, T. Otsuji, C. Tang, V. Mitin, and S. Shur, "Resonant terahertz bolometric detectors using plasmonic response in graphene-channel FETs with b-P/h-BN gate barrier layers," in The Int. IEEE Conf. on Microwaves, Communications, Antennas and Electronic Systems (IEEE COMCAS 2023), Tel-Aviv, Israel (accepted).
- [9] M. Ryzhii, V. Ryzhii, M. S. Shur, V. Mitin, C. Tang, and T. Otsuji, "Terahertz bolometric detectors based on graphene field-effect transistors with the composite h-BN/black-P/h-BN gate layers using plasmonic resonances," J. Appl. Phys., vol. 134, no. 8, 084501, 2023.
- [10] A. S. Mayorov et al, "Micrometer-scale ballistic transport in encapsulated graphene at room temperature," Nano Lett., vol. 11, no. 6, pp. 2396–2399, 2011.
- [11] M. Yankowitz, Q. Ma, P. Jarillo-Herrero, and B. J. LeRoy, "van der Waals heterostructures combining graphene and hexagonal boron nitride," Nat. Rev. Phys., vol. 1, no. 2, pp. 112–125, 2019.
- [12] M. Uda, A. Nakamura, T. Yamamoto, and Y. Fujimoto, "Work function of polycrystalline Ag, Au and Al," J. Electron. Spectrosc. Relat. Phenom., vol. 88, pp. 643–648, 1998.
- [13] S. M. Song, J. K. Park, O. J. Sul, and B. J. Cho, "Determination of work function of graphene under a metal electrode and its role in contact resistance," Nano Lett., vol. 12, no. 8, pp. 3887–3892, 2012.
- [14] F. Liu, X. Zhang, P. Gong, T. Wang, K. Yao, S. Zhu, and Yan Lu, "Potential outstanding physical properties of novel black arsenic phosphorus As(0.25)P(0.75)/As(0.75)P(0.25) phases: a first-principles investigation," RSC Adv., vol. 12, no. 6, pp. 3745–3754, 2022.
- [15] T. Hu, B. Xu, and J. Hong, "Two-dimensional As1-xPx binary compounds: Highly tunable electronic structure and optical properties," Curr. Appl. Phys., vol. 17, no. 2, pp. 186–191, 2017.
- [16] M. Xie et al, "A promising two-dimensional solar cell donor: Black arsenic–phosphorus monolayer with 1.54 eV direct bandgap and mobility exceeding 14,000 cm2/V-1s-1," Nano Energy, vol. 28, pp. 433–439, 2016.
- [17] E. P. Young et al, "Wafer-scale black arsenic–phosphorus thin-film synthesis validated with density functional perturbation theory predictions," ACS Appl. Nano Mater., vol. 1, no. 9, pp. 4737–4745, 2018.
- [18] B. Liu et al, "Black arsenic-phosphorus: Layered anisotropic infrared semiconductors with highly tunable compositions and properties," Adv. Mater., vol. 27, no. 30, pp. 4423–4429, 2015.
- [19] Q. Li, X. Xie, and S. D. Sarma, "Calculated heat capacity and magnetization of two-dimensional electron systems," Phys. Rev. B, vol. 40, no. 2, pp. 1381–1384, 1989.
- [20] M. Massicotte, G. Soavi, A. Principi, and K.-J. Tielrooij, "Hot carriers in graphene–fundamentals and applications," Nanoscale, vol. 13, no. 18, pp. 8376–8411, 2021.
- [21] Z. Tong, A. Pecchia, C. Yam, T. Dumitrică, and T. Frauenheim, "Ultrahigh electron thermal conductivity in T-Graphene, Biphenylene, and Net-Graphene," Adv. Energy Mater., vol. 12, no. 28, 2200657, 2022.
- [22] T. Y. Kim, C.-H. Park, and N. Marzari, "The electronic thermal conductivity of graphene," Nano Lett., vol. 16, no. 4, pp. 2439–2443, 2016.
- [23] V. Ryzhii, A. Satou, and T. Otsuji, "Plasma waves in two-dimensional electron-hole system in gated graphene heterostructures," J. Appl. Phys., vol. 101, no. 2, 024509, 2007.
- [24] V. Ryzhii, T. Otsuji, and M. Shur, "Graphene based plasma-wave devices for terahertz applications," Appl. Phys. Lett., vol. 116, no. 14, 140501, 2020.
- [25] J. H. Strait, H. Wang, S. Shivaraman, V. Shields, M. Spencer, and F. Rana, "Very slow cooling dynamics of photoexcited carriers in graphene observed by optical-pump terahertz-probe spectroscopy," Nano Lett., vol. 11, no. 11, pp. 4902–4906, 2011.
- [26] V. Ryzhii, M. Ryzhii, V. Mitin, A. Satou, and T. Otsuji, "Effect of heating and cooling of photogenerated electron–hole plasma in optically pumped graphene on population inversion," Jpn. J. Appl. Phys., vol. 50, no. 9R, 094001, 2011.
- [27] V. Ryzhii et al, "Graphene terahertz uncooled bolometers," J. Phys. D: Appl. Phys., vol. 46, no. 6, 065102, 2013.
- [28] V. Ryzhii et al, "Graphene vertical hot-electron terahertz detectors," J. Appl. Phys., vol. 116, no. 11, 114504, 2014.
- [29] K. Tamura et al, "Fast and sensitive terahertz detection with a current-driven epitaxial-graphene asymmetric dual-grating-gate field-effect transistor structure," APL Photonics, vol. 7, no. 12, 126101, 2022.
- [30] Y. Liu et al, "Phonon-mediated colossal magnetoresistance in graphene/black phosphorus heterostructures," Nano Lett., vol. 18, no. 6, pp. 3377–3383, 2018.
- [31] F. Vasko and V. Ryzhii, "Voltage and temperature dependencies of conductivity in gated graphene," Phys. Rev. B, vol. 76, no. 23, 233404, 2007.
- [32] E. Hwang and S. D. Sarma, "Acoustic phonon scattering limited carrier mobility in two-dimensional extrinsic graphene," Phys. Rev. B, vol. 77, no. 11, 115449, 2008.