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On the Kertész line:
Thermodynamic versus Geometric Criticality

Ph. Blanchard1, D. Gandolfo2, L. Laanait3,
J. Ruiz2, and H. Satz1
Abstract

The critical behaviour of the Ising model in the absence of an external magnetic field can be specified either through spontaneous symmetry breaking (thermal criticality) or through cluster percolation (geometric criticality). We extend this to finite external fields for the case of the Potts’ model, showing that a geometric analysis leads to the same first order/second order structure as found in thermodynamic studies. We calculate the Kertész line, separating percolating and non-percolating regimes, both analytically and numerically for the Potts model in presence of an external magnetic field.

pacs: 05.50.+q,64.60.C,75.10.H,05.70.Fh,05.10Ln

11footnotetext: Fakultät für Physik, Universität Bielefeld, D-33501, Bielefeld, Germany22footnotetext: Centre de Physique Théorique, UMR 6207, Universités Aix-Marseille et Sud Toulon-Var, Luminy Case 907, 13288 Marseille, France 33footnotetext: Ecole Normale Supérieure de Rabat, BP 5118, Rabat, Morocco

1 Introduction

The critical behaviour in certain spin systems, such as the Ising model, can be specified in two equivalent, though conceptually quite different ways. In the absence of an external magnetic field, decreasing the temperature leads eventually to the onset of spontaneous symmetry breaking and hence to the singular behaviour of derivatives of the partition function. On the other hand, the average size of clusters of like-sign spins also diverges at a certain temperature, i.e., there is an onset of percolation. The relation between these two distinct forms of singular behaviour has been studied extensively over the years, and it was shown that for the Ising model on the lattice d\mathbbm{Z}^{d}, with d2d\geq 2, implemented with a suitable cluster definition using temperature dependent bond weights, the two forms lead to the same criticality: the critical temperatures TcT_{c} as well as the corresponding critical exponents coincide in the two formulations [7, 4].

In the presence of an external field HH, the Z2Z_{2} symmetry of the Ising model is explicitly broken and hence there is no more thermodynamic critical behaviour. Geometric critical behaviour persists, however; for TTp(H)T\leq T_{p}(H), there is percolation, while for T>Tp(H)T>T_{p}(H), the average cluster size remains finite. In the THT-H plane, there thus exists a line Tp(H)T_{p}(H), the so-called Kertész line, separating a percolating from a non-percolating “phase” [11]. Given the mentioned correct cluster definition, it starts at Tp(0)=TcT_{p}(0)=T_{c}, i.e., at the thermodynamic critical point.

We want to show here that the equivalence of thermodynamic and geometric critical behaviour can be extended to the case H0H\not=0. Since in the case of continuous thermodynamic transitions, such as those of the Ising model, the introduction of an external field excludes singular behaviour (for the case d=2d=2 this is shown analytically [9, 6]), our problem makes sense only for first order transitions, for which the discontinuity remains over a certain range of HH, even though for H0H\not=0, the symmetry is broken. The ideal tool for such a study is the qq-state Potts’ model on a lattice d\mathbbm{Z}^{d}, with q3q\geq 3 and d3d\geq 3. In this case, we have a thermodynamic phase diagram of the type shown in Fig. 1a, with a line of first order transitions starting at Tc(0)T_{c}(0) and ending at a second order point Tc(Hc)T_{c}(H_{c}) [10]; the transition at this endpoint is found to be in the universality class of the 3-d Ising model. In terms of the energy density ϵ(H)\epsilon(H) of the system (the energy per lattice volume), the phase diagram has the form shown in Fig. 1b; for H=0H=0, the coexistence range ϵ2ϵ(0)ϵ1\epsilon_{2}\leq\epsilon(0)\leq\epsilon_{1} corresponds to the critical temperature Tc(0)T_{c}(0). The average spin m(ϵ)m(\epsilon) as order parameter vanishes for ϵϵ1\epsilon\geq\epsilon_{1} and becomes finite for smaller ϵ\epsilon. We want to show that in the temperature range Tc(0)T(H)Tc(Hc)T_{c}(0)\leq T(H)\leq T_{c}(H_{c}), the corresponding Kertész line Tp(H)T_{p}(H) (see Fig. 1c) coincides with that of the thermal discontinuity and that it also leads to the same first order/second order phase structure. Let us begin with a conceptual discussion of the situation.


Refer to caption

Refer to caption

Figure 1: Thermodynamic and geometric phase structure for a first order transition

The qq-state Potts’ model in the absence of an external field provides q+1q+1 phases: the disordered phase at high temperature and qq degenerate ordered low-temperature phases. Spontaneous symmetry breaking has the system fall into one of these as the temperature is decreased. Turning on a small external field HH aligns the spins in its direction and thus effectively removes the q1q-1 “orthogonal” low-temperature phases. Hence now only two phases remain: the ordered low-temperature state of spins aligned in the direction of HH, and the disordered high-temperature phase. The two are for T<Tc(Hc)T<T_{c}(H_{c}) separated by a mixed-phase coexistence regime. At the endpoint T=Tc(Hc)T=T_{c}(H_{c}), there is a continuous transition from a system in one (symmetry broken) ordered phase to the corresponding (symmetric) disordered phase. The behaviour at H=HcH=H_{c} in Fig. 1b is thus just that of the Ising model, and hence the endpoint transition is in its universality class.

In the geometric formulation for H=0H=0, with decreasing temperature or energy density there is formation of finite clusters of qq different orientations; the clusters here are defined using the temperature-dependent F-K bond weights. At ϵ(0)=ϵ1\epsilon(0)=\epsilon_{1}, the ZqZ_{q} symmetry is spontaneously broken: for one of the qq directions, there now are percolating clusters, and the percolation strength P(ϵ)P(\epsilon) becomes finite for ϵ<ϵ1\epsilon<\epsilon_{1}. However, the disordered phase also still forms a percolating medium (for d3d\geq 3). A further decrease of the energy density reduces the fraction of space in disordered state, and for ϵ(0)ϵ2\epsilon(0)\leq\epsilon_{2}, there is no more disordered percolation. Embedded in the disordered phase are at all times finite clusters of a spin orientation “orthogonal” to the one chosen by spontaneous symmetry breaking. In our treatment, we will therefore divide the set of clusters into three classes: disordered, ordered in the direction of symmetry breaking, and ordered orthogonal to the latter. While for H=0H=0, any of the qq directions could be the given orientation, for H0H\not=0, the external field specifies the alignment direction, making the q1q-1 sets of “orthogonal” clusters essentially irrelevant. It is for this reason that at the endpoint of a line of first order transitions one generally encounters the universality class of the Ising model. Whatever the original symmetry of the system was, at the endpoint there remains only the aligned and the disordered ground states.

The plan of the paper is as follows. In the next section, we recall the cluster treatment of the Potts’ model and specify our method to identify the different cluster types. This will be followed by an analytic study valid for small external fields and by numerical calculations for different qq up to asymptotic values of HH. Formal details of the analytic calculation are given in the appendix.

2 The model

We consider a finite–volume qq–state Potts model on the lattice d\mathbbm{Z}^{d} (d2d\geq 2), at inverse temperature β=1/T\beta=1/T and subject to an external ordering field hh. It is defined by the Boltzmann weight

ωPotts(𝝈)=i,jeβ(δσi,σj1)iehδσi,1,\omega_{\operatorname{Potts}}(\boldsymbol{\sigma})=\prod_{\langle i,j\rangle}e^{\beta(\delta_{\sigma_{i},\sigma_{j}}-1)}\prod_{i}e^{h\delta_{\sigma_{i},1}}, (1)

where the spins σi\sigma_{i} take on the values of the set {1,,q}\{1,\ldots,q\}, and where the first product is over nearest neighbour pairs (n,n). If we want to study the behaviour of clusters, in the sense of F-K clusters, we turn to the corresponding Edwards–Sokal formulation [5], given by the Boltzmann weight

ωES(𝝈,𝜼)=i,j[eβδηij,0+(1eβ)δηij,1δσi,σj]iehδσi,1,\omega_{\operatorname{ES}}(\boldsymbol{\sigma},\boldsymbol{\eta})=\prod_{\langle i,j\rangle}[e^{-\beta}\delta_{\eta_{ij},0}+(1-e^{-\beta})\delta_{\eta_{ij},1}\delta_{\sigma_{i},\sigma_{j}}]\prod_{i}e^{h\delta_{\sigma_{i},1}}, (2)

where the edge variables ηij\eta_{ij} belong to {0,1}\{0,1\}. This “site-bond” model can be thought of as follows. Given a certain spin configuration, one puts between two neighbouring sites σi=σj\sigma_{i}=\sigma_{j} an edge or bond with the probability 1eβ1-e^{-\beta}, and no edge with the probability eβe^{-\beta}; for σiσj\sigma_{i}\neq\sigma_{j}, no bond is present. When the field is infinite, all σi=1\sigma_{i}=1, and we are left with a classical bond percolation problem, while for finite field, one has a random bond percolation model in the random media given by the spin configuration.

In the presence of an external field, we find it convenient for the study of the Kertész’s line to consider a modified version of the Edwards–Sokal formulation. We have three different types of spin combination: (0) two adjacent spins i,ji,j are not equal, (1) two adjacent spins i,ji,j are equal and parallel to hh (we denote this direction as 1), or (2) two adjacent spins i,ji,j are equal but not parallel to hh. Correspondingly, we “color” the edge between ii and jj in three different colors ni,jn_{i,j}, where the edge variables nijn_{ij} belong to {0,1,2}\{0,1,2\}. The resulting Boltzmann weight becomes

ωCES(𝝈,𝒏)=i,j[eβδnij,0+(1eβ)δnij,1χ(σi=σj=1)+(1eβ)δnij,2χ(σi=σj1)]iehδσi,1,\omega_{\operatorname{CES}}(\boldsymbol{\sigma},\boldsymbol{n})=\prod_{\langle i,j\rangle}[e^{-\beta}\delta_{n_{ij},0}+(1-e^{-\beta})\delta_{n_{ij},1}\chi_{(\sigma_{i}=\sigma_{j}=1)}\\ +(1-e^{-\beta})\delta_{n_{ij},2}\chi_{(\sigma_{i}=\sigma_{j}\neq 1)}]\prod_{i}e^{h\delta_{\sigma_{i},1}}, (3)

where the characteristic function χ(σi=σj=1)\chi(\sigma_{i}=\sigma_{j}=1) is unity for σi=σj=1\sigma_{i}=\sigma_{j}=1 (parallel spins in the direction of hh) and zero otherwise, while χ(σi=σj1)\chi(\sigma_{i}=\sigma_{j}\neq 1) is unity for parallel spins not in the direction of hh and zero otherwise. The summation over the spin variables then leads to the following Tricolor–Edge–Representation

ωTER(𝒏)=i,jeβδnij,0(1eβ)(δnij,1+δnij,2)×ehS1(𝒏)(q1)C2(𝒏)(q1+eh)|Λ|S1(𝒏)S2(𝒏).\omega_{\operatorname{TER}}(\boldsymbol{n})=\prod_{\langle i,j\rangle}e^{-\beta\delta_{n_{ij},0}}(1-e^{-\beta})^{(\delta_{n_{ij},1}+\delta_{n_{ij},2})}\times\\ e^{hS_{1}(\boldsymbol{n})}(q-1)^{C_{2}(\boldsymbol{n})}(q-1+e^{h})^{|\Lambda|-S_{1}(\boldsymbol{n})-S_{2}(\boldsymbol{n})}. (4)

Here, S1(𝒏)S_{1}(\boldsymbol{n}) and S2(𝒏)S_{2}(\boldsymbol{n}) denote the number of sites that belong to edges of color 11 and color 22, respectively, while C2(𝒏)C_{2}(\boldsymbol{n}) denotes the number of connected components of the set of edges of color 22, and |Λ||\Lambda| is the number of sites of the lattice under consideration.

Let us mention that such kind of graphical representation has already been considered for various spin models in presence of an external field [3].

Let pΛ(ij)p_{\Lambda}(i\leftrightarrow j) be the probability that the site ii is connected to jj by a path of edges of color 11. As (geometric) order parameter we will consider the following mass–gap (inverse correlation length)

m(β,h)=lim|ij|1|ij|lnlimΛdpΛ(ij)m(\beta,h)=-\lim_{|i-j|\rightarrow\infty}\frac{1}{|i-j|}\ln\lim_{\Lambda\uparrow\mathbbm{Z}^{d}}p_{\Lambda}(i\leftrightarrow j) (5)

where ii and jj belong to some line parallel to an axis of the lattice. As (thermodynamic) order parameter, we shall consider the mean energy E(β,h)=1ββf(β,h)E(\beta,h)=-\frac{1}{\beta}\frac{\partial}{\partial\beta}f(\beta,h), where f(β,h)f(\beta,h) is the free energy of the model 444 Note that all partitions functions, and hence the free energies, of models (1 )–(4 ) coincide .

3 Analytic results

Let us first have a look at the diagram of ground state configurations of the TER representation which are the translation invariant configurations maximizing the Boltzmann weight (4).

For the color a=0,1,2a=0,1,2, let bab_{a} be the value of the Boltzmann weight of the ground state configuration of color aa per unit site. One finds b0=eβd(q1+eh),b1=(1eβ)deh,b2=(1eβ)db_{0}=e^{-\beta d}(q-1+e^{h}),b_{1}=(1-e^{-\beta})^{d}e^{h},b_{2}=(1-e^{-\beta})^{d}.

Notice that b0=b1b_{0}=b_{1} on the line

β0(h)=ln[1+(1+(q1)eh)1/d]\beta_{0}(h)=\ln[1+(1+(q-1)e^{-h})^{1/d}] (6)

and that b0=b1=b2b_{0}=b_{1}=b_{2} at the point β0(0)\beta_{0}(0).

The diagram of ground state configurations, inferred from the values of the weights b0,b1,b2b_{0},b_{1},b_{2} is shown in Fig. 2 (in the (h,β)(h,\beta) plane).

Refer to caption
Figure 2: Diagram of ground state configurations: All the ground state configurations coexist at (0,β0(0))(0,\beta_{0}(0)). Below β0(h)\beta_{0}(h), the 0–state dominates. Above β0(h)\beta_{0}(h), the 11–state dominates; it coexists with the 0–state on the line β0(h)\beta_{0}(h), and with the 22–state on the line h=0h=0, ββ0(0)\beta\geq\beta_{0}(0).

When qq is large enough and hh not too large, the TER representation (4) can be analyzed rigorously by a perturbative approach. Namely, by using the standard machinery of Pirogov–Sinai theory, we will show that the model undergoes a thermodynamic first order phase transition in the sense that the mean energy (as well as the magnetization) is discontinuous at some βc(h)β0(h)\beta_{c}(h)\sim\beta_{0}(h). We also find for these values of the parameters, that the phase diagram of this model reproduces the diagram of ground state configurations (Fig. 2), see Appendix for more details.

In addition, the model exhibits a geometric (first order) transition, in the sense that, on the same critical line, the mass gap is discontinuous.

Theorem 1.

Assume d2d\geq 2, qq and hh such that

cd(1+(q1)eh)1/2d<1c_{d}(1+(q-1)e^{-h})^{-1/2d}<1 (7)

holds, where cdc_{d} is a given number (depending only on the dimension), then there exists a unique βc(h)=β0(h)+O(1+(q1)eh)1/2d)\beta_{c}(h)=\beta_{0}(h)+O(1+(q-1)e^{-h})^{-1/2d}) such that

  1. 1.

    ΔE(βc(h),h)=E(βc(h),h)E(βc+(h),h)>0\Delta E(\beta_{c}(h),h)=E(\beta^{-}_{c}(h),h)-E(\beta^{+}_{c}(h),h)>0

  2. 2.

    m(β,h)>0m(\beta,h)>0 for ββc(h)\beta\leq\beta_{c}(h) and m(β,h)=0m(\beta,h)=0 for β>βc(h)\beta>\beta_{c}(h).

The proof is given in the appendix.

Let us recall that it has already been shown that the Potts model (1) undergoes, for qq large and hh small, a first order phase transition on a critical line [1], where both the mean energy and the magnetization are discontinuous. Since, as already mentioned, the free energies of models (1) and (4) are the same, this critical line coincides with the one mentioned in the theorem.

In the absence of an external magnetic field, the statements of the theorem have been shown previously [13, 14, 12].

Condition (7) restricts the range of values of parameters to which our rigorous analysis applies. Moreover, we do not expect thermodynamic first order transitions when hh is sufficiently enhanced. In the next section, we turn to numerical study on a wider range of values.

4 Numerical simulations

We have implemented a generalization of the Swendsen–Wang algorithm for our colored Edwards–Sokal model (3).

First, given a spin configuration, we put between any two neighbouring spins of the same color, an edge colored 0 with probability (w.p.) eβe^{-\beta}, and w.p. 1eβ1-e^{-\beta}, an edge colored 11 if these spins are of color 11, and colored 22 otherwise. When two neighbouring spins disagree, the corresponding edge is colored 0.

Then, starting from an edge configuration, a spin configuration is constructed as follows. Isolated sites (endpoints of 0–bonds only) are colored 11 w.p. eh/(q1+eh)e^{h}/(q-1+e^{h}) and colored c{2,,q}c\in\{2,...,q\} w.p. 1/(q1+eh)1/(q-1+e^{h}). Non–isolated sites are colored 11 (w.p. 1) if they are endpoints of 11–bonds and colored c{2,,q}c\in\{2,...,q\} w.p. 1/(q1)1/(q-1).

This algorithm allows us two compute both quantities associated to spins configurations and those associated to edges configurations.

The numerical results for d=2d=2 are presented in Fig. 3. For q4q\leq 4, we found a whole geometric transition line βc(h)\beta_{c}(h) for which m(β,h)>0m(\beta,h)>0 when β<βc(h)\beta<\beta_{c}(h), and m(β,h)=0m(\beta,h)=0 when ββc(h)\beta\geq\beta_{c}(h). The mass gap is continuous at βc(h)\beta_{c}(h). For β<βc(h)\beta<\beta_{c}(h), the mean cluster sizes remain finite, while for ββc(h)\beta\geq\beta_{c}(h) the size of 11–edge clusters diverges. The energy density as well as the magnetization do not show any singular behavior.

For q5q\geq 5, some critical hch_{c} appears for which the geometric transition line βc(h)\beta_{c}(h) becomes first order when h<hch<h_{c}, i.e. m(β,h)>0m(\beta,h)>0 for ββc(h)\beta\leq\beta_{c}(h) and m(β,h)=0m(\beta,h)=0 for β>βc(h)\beta>\beta_{c}(h). In addition, on this part of the line, we find that the mean energy is discontinuous 555The Swendsen-Wang algorithm allows to compute both associated order parameters (mass-gap and mean energy).. When hhch\geq h_{c}, only a geometric transition occurs and the scenario is the same as for q4q\leq 4. Thus our numerics show that the geometric and thermodynamic transitions coincide up to hch_{c}, similarly to what we got analytically but only at (very) small field (and large qq), see Fig. 3.

Let us mention that the numerics are in accordance with the theory for vanishing and infinite fields: βc(0)=ln(1+q)\beta_{c}(0)=\ln(1+\sqrt{q}) and βc()=ln2\beta_{c}(\infty)=\ln 2.

Refer to caption
Figure 3: βc(h)\beta_{c}(h) for several values of qq, with “first order” behavior in red, “second order” in blue. The first order behavior is both thermodynamic and geometric. The second order behavior is only geometric.

The system size in these calculations was L=50L=50, d=2d=2. The “first order” part of the transition lines has been determined via Binder cumulants [2]. The Hoshen-Kopelman algorithm [8] was used to study cluster statistics. For each value of qq, more than 2×1052\times 10^{5} iterations were performed. Data have been binned in order to control errors in measurements.

5 Concluding remarks

For the Potts model in the presence of an external magnetic field, we have shown that when the Kertész line is first order, it coincides with the usual thermodynamic critical line. This property holds up to some critical point (hc,βc(hc))(h_{c},\beta_{c}(h_{c})), beyond which the thermodynamic transition disappears. Such behavior may well appear also for a broader class of models exhibiting first order transition in the presence of an external field. We believe that the behavior at the above critical point also belongs to the universality class of the Ising model, as it is the case in the 33–state Potts model in three dimensions [10].

6 Acknowledgements

It is a pleasure to thank János Kertész for interesting comments. The BIBOS research center (Bielefeld) and the Centre de Physique Théorique (CNRS Marseille) are gratefully acknowledged for warm hospitality and financial support. The authors are indebted to an anonymous referee for constructive remarks.

7 Appendix

We first introduce the partition function of the TER representation with boundary conditions a{0,1,2}a\in\{0,1,2\} in a box Λ\Lambda 666The reader should not be confused by the fact that (8), called diluted partition function in PS–theory, differs from the usual one by an unimportant boundary term which makes the expansions (10) and (11) easier to write.:

Za(Λ)=𝒏iΛωi(𝒏)qC2(𝒏)δa,2iΛjiδnij,aZ_{a}(\Lambda)=\sum_{\boldsymbol{n}}\prod_{i\in\Lambda}\omega_{i}(\boldsymbol{n})q^{C_{2}(\boldsymbol{n})-\delta_{a,2}}\prod_{i\in\partial\Lambda}\prod_{j\sim i}\delta_{n_{ij},a} (8)

where the sum is over all configurations 𝒏={nij}ijΛ\boldsymbol{n}=\{n_{ij}\}_{ij\cap\Lambda\emptyset}, Λ\partial\Lambda is the boundary of Λ\Lambda (set of sites of Λ\Lambda with a n.n. in dΛ\mathbbm{Z}^{d}\setminus\Lambda), the notation iji\sim j means that ii and jj are n.n., and

ωi(𝒏)=(1eβ)(δnij,1+δnij,2)/2eβδnij,0/2ehχ(i1′′)(q1+eh)jiδnij,0\omega_{i}(\boldsymbol{n})=(1-e^{-\beta})^{(\delta_{n_{ij},1}+\delta_{n_{ij},2})/2}e^{-\beta\delta_{n_{ij},0}/2}e^{h\chi(i\in``1^{\prime\prime})}(q-1+e^{h})^{\prod_{j\sim i}\delta_{n_{ij},0}} (9)

where χ(i1′′)\chi(i\in``1^{\prime\prime}) means that the site ii belongs to some edge of color 11. Next, consider a configuration𝒏\boldsymbol{n} on the envelope of Λ\Lambda: E(Λ)={i,jΛ}E(\Lambda)=\{\langle i,j\rangle\cap\Lambda\neq\emptyset\}. A site iΛi\in\Lambda is called correct if for all jij\sim i, nijn_{ij} takes the same value, and called incorrect otherwise. Denote I(𝒏)I(\boldsymbol{n}) the set of incorrect sites of the configuration 𝒏\boldsymbol{n}. A couple Γ={SuppΓ,𝒏(Γ)}\Gamma=\{\operatorname{Supp}\Gamma,\boldsymbol{n}(\Gamma)\} where the support of Γ\Gamma (SuppΓ\operatorname{Supp}\Gamma) is a maximal connected subset of I(𝒏)I(\boldsymbol{n}), and 𝒏(Γ)\boldsymbol{n}(\Gamma) the restriction of 𝒏\boldsymbol{n} to the envelope of Λ\Lambda is called contour of the configuration 𝒏\boldsymbol{n} (here, a set of sites is called connected if the graph that joins all the sites of this set at distance d(i,j)=maxk=1,,d|ikjk|1d(i,j)=\max_{k=1,\ldots,d}|i_{k}-j_{k}|\leq 1 is connected). A couple Γ={SuppΓ,𝒏(Γ)}\Gamma=\{\operatorname{Supp}\Gamma,\boldsymbol{n}(\Gamma)\} where SuppΓ\operatorname{Supp}\Gamma is a connected set of sites is called contour if there exists a configuration 𝒏\boldsymbol{n} such that Γ\Gamma is a contour of 𝒏\boldsymbol{n}. For a contour Γ\Gamma, let 𝒏Γ\boldsymbol{n}_{\Gamma} denote the configuration having Γ\Gamma as unique contour, ExtΓ\operatorname{Ext}\Gamma denotes the unique infinite component of d(SuppΓ)\mathbbm{Z}^{d}\setminus(\operatorname{Supp}\Gamma), IntΓ=d(ExtΓSuppΓ)\operatorname{Int}\Gamma=\mathbbm{Z}^{d}\setminus(\operatorname{Ext}\Gamma\cup\operatorname{Supp}\Gamma), and IntmΓ\operatorname{Int}_{m}\Gamma denote the set of sites of IntΓ\operatorname{Int}\Gamma corresponding to the color m{0,1,2}m\in\{0,1,2\} for the configuration 𝒏Γ\boldsymbol{n}_{\Gamma}. Two contours Γ1\Gamma_{1} and Γ2\Gamma_{2} are said to be compatible if their union is not connected and are called external contours if furthermore IntΓ1ExtΛΓ2\operatorname{Int}\Gamma_{1}\subset\operatorname{Ext}_{\Lambda}\Gamma_{2} and IntΓ2ExtΛΓ1\operatorname{Int}\Gamma_{2}\subset\operatorname{Ext}_{\Lambda}\Gamma_{1}. For a family θ={Γ1,,Γn}ext\theta=\{\Gamma_{1},\ldots,\Gamma_{n}\}_{\operatorname{ext}} of external contours, let ExtΛθ\operatorname{Ext}_{\Lambda}\theta denote the intersection Λk=1nExtΛΓk\Lambda\cap_{k=1}^{n}\operatorname{Ext}_{\Lambda}\Gamma_{k}. With these definitions and notations, one gets the following expansion of the partition functions over families of external contours,

Za(Λ)=θ={Γ1,,Γn}extba|ExtΛθ|k=1nρ(Γk)m=0,1,2Zm(IntmΓk),Z_{a}(\Lambda)=\sum_{\theta=\{\Gamma_{1},\ldots,\Gamma_{n}\}_{\operatorname{ext}}}b_{a}^{|\operatorname{Ext}_{\Lambda}\theta|}\prod_{k=1}^{n}\rho(\Gamma_{k})\prod_{\text{$m=0,1,2$}}Z_{m}(\operatorname{Int}_{{}_{m}}\Gamma_{k}), (10)

where ρ(Γ)=isuppΓωi(𝒏Γ)qC(𝒏Γ)δa,2\rho(\Gamma)=\prod_{i\in\operatorname{supp}\Gamma}\omega_{i}(\boldsymbol{n}_{\Gamma})q^{C(\boldsymbol{n}_{\Gamma})-\delta_{a,2}}. From (10), we get

Za(Λ)=ba|Λ|{Γ1,,Γn}compk=1nza(Γk),Z_{a}(\Lambda)=b_{a}^{|\Lambda|}\sum_{\{\Gamma_{1},\ldots,\Gamma_{n}\}_{\operatorname{comp}}}\prod_{k=1}^{n}z_{a}(\Gamma_{k}), (11)

where the sum is now over families of compatible contours and the activities za(Γ)z_{a}(\Gamma) of contours are given by za(Γ)=ρ(Γ)ba|suppΓ|maZm(IntmΓ)Za(IntmΓ)z_{a}(\Gamma)=\rho(\Gamma)b_{a}^{-|\operatorname{supp}\Gamma|}\prod_{m\neq a}\frac{Z_{m}(\operatorname{Int}_{{}_{m}}\Gamma)}{Z_{a}(\operatorname{Int}_{{}_{m}}\Gamma)}.

It is easy to prove the following Peierls’ estimate,

ρ(Γ)(maxa=0,1,2ba)|SuppΓ|eτ|SuppΓ|,\rho(\Gamma)(\max_{a=0,1,2}b_{a})^{-|\operatorname{Supp}\Gamma|}\leq e^{-\tau|\operatorname{Supp}\Gamma|}, (12)

where eτ=(1+(q1)eh)1/2de^{-\tau}=(1+(q-1)e^{-h})^{-1/2d}. Indeed, first notice that an incorrect site ii is either of color 11 or of color 22. In the first case one has ji(δnij,0+δnij,1)=2d\sum_{j\sim i}(\delta_{n_{ij},0}+\delta_{n_{ij},1})=2d, so that ωi(𝒏Γ)/b1=(eβ1)(jiδnij,0)/2\omega_{i}(\boldsymbol{n}_{\Gamma})/b_{1}=(e^{\beta}-1)^{-(\sum_{j\sim i}\delta_{n_{ij},0})/2}, implying

ωi(𝒏Γ)/maxa=0,1,2ba(1+(q1)eh)(jiδnij,0)/2d.\omega_{i}(\boldsymbol{n}_{\Gamma})/\max_{a=0,1,2}b_{a}\leq(1+(q-1)e^{-h})^{-(\sum_{j\sim i}\delta_{n_{ij},0})/2d}.

Thus since 1jiδnij,02d11\leq\sum_{j\sim i}\delta_{n_{ij},0}\leq 2d-1, each incorrect site of color 11 gives at most a contribution eτe^{-\tau} to the L.H.S. of (12). In the second case, one has ji(δnij,0+δnij,2)=2d\sum_{j\sim i}(\delta_{n_{ij},0}+\delta_{n_{ij},2})=2d, so that wi(𝒏Γ)/b2=(eβ1)(jiδnij,0)/2,w_{i}(\boldsymbol{n}_{\Gamma})/b_{2}=(e^{\beta}-1)^{-(\sum_{j\sim i}\delta_{n_{ij},0})/2}, implying

ωi(𝒏Γ)/maxa=0,1,2ba(q1+eh)(jiδnij,0)/2d.\omega_{i}(\boldsymbol{n}_{\Gamma})/\max_{a=0,1,2}b_{a}\leq(q-1+e^{h})^{-(\sum_{j\sim i}\delta_{n_{ij},0})/2d}.

We then use again that 1jiδnij,02d11\leq\sum_{j\sim i}\delta_{n_{ij},0}\leq 2d-1 and that C2(𝒏Γ)iSuppΓχ(1δnij,2)/2jiδnij,2C_{2}(\boldsymbol{n}_{\Gamma})\leq\sum_{i\in\operatorname{Supp}\Gamma}\chi(1\leq\delta_{n_{ij},2})/2^{\sum_{j\sim i}\delta_{n_{ij},2}} (see [12]) to obtain that each incorrect site of color 22 gives at most a contribution (eh+q1)1/2+1/2deτ(e^{h}+q-1)^{-1/2+1/2d}\leq e^{-\tau} to the L.H.S. of (12).

When the assumptions of the theorem are satisfied, the Peierls’ estimate (12) provides a good control of the system by using Pirogov–Sinai theory [15]. We introduce the truncated activity

za(Γ)={za(Γ)ifza(Γ)(c0eτ)|SuppΓ|(c0eτ)|SuppΓ|otherwise,z_{a}^{\prime}(\Gamma)=\left\{\begin{array}[]{l}z_{a}(\Gamma)\operatorname{if}z_{a}(\Gamma)\leq(c_{0}e^{-\tau})^{|\operatorname{Supp}\Gamma|}\\ (c_{0}e^{-\tau})^{|\operatorname{Supp}\Gamma|}\operatorname{otherwise,}\end{array}\right.

where c0c_{0} is a numerical constant, and we call a contour stable if za(Γ)=za(Γ)z_{a}(\Gamma)=z_{a}^{\prime}(\Gamma). Let Za(Λ)Z_{a}^{\prime}(\Lambda) be the partition function obtained from (11) by leaving out unstable contours, i.e., by taking the activities za(Γ)z_{a}^{\prime}(\Gamma) in (11), and let us introduce the metastable free energies famet(β,h)=limΛd(1/|Λ|)lnZa(Λ)f^{\operatorname{met}}_{a}(\beta,h)=-\lim_{\Lambda\uparrow\mathbbm{Z}^{d}}(1/|\Lambda|)\ln Z_{a}^{\prime}(\Lambda). The leading term of these metastable free energies equals lnba-\ln b_{a}. The corrections can be expressed by free energies of contour models which can be controlled by convergent cluster expansions. As a standard result of Pirogov-Sinai theory, one gets that the phase diagram of the system is a small perturbation of the diagram of ground state configurations. Namely, there exits a unique point βc(0)\beta_{c}(0) given by the solution of f0met(β,h)=f1met(β,h)=f2met(β,h)f_{0}^{\operatorname{met}}(\beta,h)=f_{1}^{\operatorname{met}}(\beta,h)=f_{2}^{\operatorname{met}}(\beta,h) for which all contours are stable and such that Za(Λ)=Za(Λ)Z_{a}(\Lambda)=Z_{a}^{\prime}(\Lambda) for a=0,1,2a=0,1,2. There exists a line βc(h)\beta_{c}(h) given by the solution of f0met(β,h)=f1met(β,h)f_{0}^{\operatorname{met}}(\beta,h)=f_{1}^{\operatorname{met}}(\beta,h) when h>0h>0 and such that, Za(Λ)=Za(Λ)Z_{a}(\Lambda)=Z_{a}^{\prime}(\Lambda) for a=0,1a=0,1. For β<βc(h)\beta<\beta_{c}(h) one has Z0(Λ)=Z0(Λ)Z_{0}(\Lambda)=Z_{0}^{\prime}(\Lambda), and for β>βc(h)\beta>\beta_{c}(h) one has Z1(Λ)=Z1(Λ)Z_{1}(\Lambda)=Z_{1}^{\prime}(\Lambda). For h=0h=0 and ββc(0)\beta\geq\beta_{c}(0), one has in addition Z2(Λ)=Z2(Λ)Z_{2}(\Lambda)=Z_{2}^{\prime}(\Lambda).

For the color a=0,1,2a=0,1,2, denote by a(β,h)\langle\cdot\rangle^{a}(\beta,h) the expectation value under the aa–boundary condition. As a consequence of the above expansions and analysis, we obtain by standard Peierls’ estimates that for h0h\geq 0

δnij,11(β,h)\displaystyle\langle\delta_{n_{ij},1}\rangle^{1}(\beta,h) \displaystyle\geq 1O(eτ)forββc(h)\displaystyle 1-O(e^{-\tau})\quad\text{for}\quad\beta\geq\beta_{c}(h) (13)
δnij,00(β,h)\displaystyle\langle\delta_{n_{ij},0}\rangle^{0}(\beta,h) \displaystyle\geq 1O(eτ)forββc(h)\displaystyle 1-O(e^{-\tau})\quad\text{for}\quad\beta\leq\beta_{c}(h) (14)

while in addition we also get for h=0h=0:

δnij,22(β,0)1O(eτ)forββc(0)\langle\delta_{n_{ij},2}\rangle^{2}(\beta,0)\geq 1-O(e^{-\tau})\quad\text{for}\quad\beta\geq\beta_{c}(0) (15)

By definition of the mean energy, one has that ΔE=E(β,h)E(β+,h)\Delta E=E(\beta^{-},h)-E(\beta^{+},h) is proportional to the difference δnij,00(β,h)δnij,01(β,h)\langle\delta_{n_{ij},0}\rangle^{0}(\beta^{-},h)-\langle\delta_{n_{ij},0}\rangle^{1}(\beta,h), and the first statement of the theorem follows immediately from these properties.

To prove the second statement, we remark that if one imposes that the site ii is connected to jj by a path made up of edges of color 11, then under the boundary condition 0, there exists necessarily an external contour that encloses both the sites ii and jj. As a consequence of the above analysis the probability of external contours Γ\Gamma decays like (c0e)τ|SuppΓ|(c_{0}e)^{-\tau|\operatorname{Supp}\Gamma|} when the 0–contours are stable, i.e. when Z0(Λ)=Z0(Λ)Z_{0}(\Lambda)=Z_{0}^{\prime}(\Lambda). One thus gets pΛ(ij)(Cteeτ)|ij|p_{\Lambda}(i\leftrightarrow j)\leq(\operatorname{Cte}e^{-\tau})^{|i-j|} when ββc(h)\beta\leq\beta_{c}(h) from which the first statement of the theorem follows. On the other hand under the boundary condition 11, the probability that the site ii is not connected to jj can be bounded from above by a small number O(eτ)O(e^{-\tau}) when Z1(Λ)=Z1(Λ)Z_{1}(\Lambda)=Z_{1}^{\prime}(\Lambda). This follows also from a Peierls type arguments and implies that the probability that the site ii is connected to jj under the boundary condition 11 is greater than 10(eτ)1-0(e^{-\tau}) for ββc(h)\beta\geq\beta_{c}(h). It gives also that the probability pΛ(ij)p_{\Lambda}(i\leftrightarrow j) for the site ii to be connected with jj under the boundary condition 0 is also greater than 10(eτ)1-0(e^{-\tau}) for β>βc(h)\beta>\beta_{c}(h), implying the second statement.

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