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QQ-Deformed Rainbows: a Universal Simulator of Free Entanglement Spectra

Lucy Byles pylsb@leeds.ac.uk School of Physics and Astronomy, University of Leeds, Leeds, LS2 9JT, United Kingdom    Germán Sierra Instituto de Física Teórica UAM/CSIC, Universidad Autónoma de Madrid, Madrid, 28049, Spain    Jiannis K. Pachos School of Physics and Astronomy, University of Leeds, Leeds, LS2 9JT, United Kingdom
Abstract

The behaviour of correlations across a bipartition is an indispensable tool in diagnosing quantum phases of matter. Here we present a spin chain with position-dependent XX couplings and magnetic fields, that can reproduce arbitrary structure of free fermion correlations across a bipartition. In particular, by choosing appropriately the strength of the magnetic fields we can obtain any single particle energies of the entanglement spectrum with high fidelity. The resulting ground state can be elegantly formulated in terms of qq-deformed singlets. To demonstrate the versatility of our method we consider certain examples, such as a system with homogeneous correlations and a system with correlations that follow a prime number decomposition. Hence, our entanglement simulator can be easily employed for the generation of arbitrary entanglement spectra with possible applications in quantum technologies and condensed matter physics.

I Introduction

Entanglement lies at the heart of the disparity between classical and quantum mechanics. As such it has long been at the forefront of both theoretical [1, 2] and experimental [3, 4] investigations into the foundations of quantum mechanics. More recently, entanglement has gained renewed interest with the development of quantum information theory [5, 6]. In this framework, quantum entanglement is viewed as a valuable resource [7], with several quantum protocols, such as teleportation [8], able to be realised exclusively with the use of entangled states. This new focus has stimulated intensive research into how specific patterns of entanglement can be created and manipulated in quantum many-body systems [9].

One such controllable entanglement property is the scaling of the entanglement entropy, SAS_{A}, within a bipartite system. The ground states of local quantum lattice Hamiltonians typically obey an ‘area law’ such that the entanglement entropy is proportional to the size of the boundary of the chosen subsystem, AA [10, 11]. In 2010, Vitagliano, Riera and Latorre showed how tuning the coupling profile of the inhomogeneous XX model allows its ground state to transition smoothly from obeying an area law of entanglement entropy scaling to a volume law [12]. The ground state of this model is termed the ‘concentric singlet phase’ [12] or simply ‘rainbow state’ [13], due to its distinctive structure of maximally entangled valence bonds connecting pairs of sites distributed symmetrically across the centre of the chain. This simple model hosts a rich variety of properties [14, 15] and has been the subject of much interest in recent years [16, 17, 18, 19].

In this work we present a generalisation of the rainbow state model, whereby, with the introduction of staggered transverse field terms to the inhomogeneous XX model, the degree of entanglement between each concentric pair on the chain can be independently varied. Using a Real-Space Renormalization Group approach we derive recursive expressions for the induced effective coupling and transverse field terms. These expressions have an elegant description in terms of the formalism of qq-deformed algebra [20, 21]. For a chain of 2N2N sites the ground state is a tensor product of NN concentric qq-deformed singlets, each with an associated deformation parameter, qiq_{i}, dependent on the transverse field and coupling parameters of our model. The variation of these physical parameters allows for the generation of any arbitrary set of single-particle entanglement energies. To verify the validity of our results we perform a detailed numerical analysis. This analysis reveals that appropriate choices of the values of the transverse field parameter, and ordering of the degree of entanglement ensures a high fidelity between the exact ground state and the qq-deformed rainbow. Moreover, we consider two special cases to demonstrate the applicability of our method. First, we consider the case q1=q2==qNq_{1}=q_{2}=\dots=q_{N} such that each concentric pair has the same degree of entanglement. Second, we consider the case where the single-particle entanglement energies follow the ‘prime number spectrum’. This prime number decomposition employs the Moebius function to naturally mirror the entanglement spectra of free fermionic systems.

While our quantum simulator gives rise to effective couplings between sites on opposite ends of our chain, our model is completely local, given in terms of XX interactions and local magnetic fields. Thus, it directly lends itself to experimental verification and practical applications. Indeed, recent developments in cold atom experiments [22, 23, 24, 25, 26, 27] have offered unique opportunities to simulate such systems and access quantities related to entanglement [28, 29, 30, 31, 32, 33]. We expect that our quantum simulator can have direct applications in condensed matter or quantum technologies where specific structures of correlation patterns are requested between two subsystems.

II The qq-Deformed Model

In order to introduce our model for a chain of 2N2N spin-12{1\over 2} particles, we first present a two-site Hamiltonian that allows for direct continuous variation of the degree of entanglement between its spins.

II.1 Two Spins Hamiltonian

Consider the two-spins Hamiltonian

=J1(σ1xσ1x+σ1yσ1y)+h1(σ1zσ1z).\mathcal{H}=J_{1}\left(\sigma_{-1}^{x}\sigma_{1}^{x}+\sigma_{-1}^{y}\sigma_{1}^{y}\right)+h_{1}\left(\sigma_{-1}^{z}-\sigma_{1}^{z}\right). (1)

The ground state of \mathcal{H} is given by

|ψ1=1[2]q1(q112|1,1q112|1,1),\ket{\psi_{1}}=\frac{1}{\sqrt{[2]_{q_{1}}}}\left(q_{1}^{-\frac{1}{2}}\ket{\uparrow\downarrow}_{-1,1}-q_{1}^{\frac{1}{2}}\ket{\downarrow\uparrow}_{-1,1}\right), (2)

and has ground state energy

E1=[2]q1J1,E_{1}=-[2]_{q_{1}}J_{1}, (3)

where

q1=eγ1,sinhγ1=h1J1,q_{1}=e^{\gamma_{1}},\hskip 5.69046pt\sinh{\gamma_{1}}=\frac{h_{1}}{J_{1}}, (4)

and [x]q[x]_{q} is the so-called quantum dimension

[x]q=qxqxqq1.[x]_{q}=\frac{q^{x}-q^{-x}}{q-q^{-1}}. (5)

This ground state is the singlet of the quantum group SU(2)q1SU(2)_{q_{1}} [34]. Such qq-deformed valence bonds have been considered in relation to a range of quantum many-body models [35, 36, 37, 38], including the anisotropic qq-deformed generalization of the spin-11 AKLT chain as considered in [39, 40]. In the limit h10h_{1}\rightarrow 0 such that q11q_{1}\rightarrow 1, we recover the maximally entangled singlet state of the standard SU(2)SU(2) Lie algebra. The degree of entanglement between this pair is directly related to the value of the deformation parameter, q1q_{1}, which is in turn directly related to our coupling and transverse field parameters via equation (4). To investigate this, we bipartition the system down the centre of the chain into region AA, and its complement BB. The reduced density matrix of (2) is then determined for region AA. The corresponding Renyi entropy of order α\alpha is given by

SA,1(α)=11αln(1+q12α(1+q12)α),α>0,α1S_{A,1}^{(\alpha)}=\frac{1}{1-\alpha}\ln{\frac{1+q_{1}^{2\alpha}}{(1+q_{1}^{2})^{\alpha}}},\hskip 14.22636pt\alpha>0,\alpha\neq 1 (6)

and takes the maximum value ln(2)\ln{2} when q1=1q_{1}=1 for all α\alpha as shown in Figure 1. This expression for the Renyi entropy reflects a symmetry of our model as under the transformation h1h1h_{1}\rightarrow-h_{1}, such that q11q1q_{1}\rightarrow\frac{1}{q_{1}}, the value of the Renyi entropy of order α\alpha is unchanged.

By considering the limit of SA,1(α)S_{A,1}^{(\alpha)} as α1\alpha\rightarrow 1 we obtain the expression for the von Neumann entanglement entropy of the pair

SA,1=ln((1+q12))q121+q12ln(q12).S_{A,1}=\ln{(1+q_{1}^{2})}-\frac{q_{1}^{2}}{1+q_{1}^{2}}\ln{q_{1}^{2}}. (7)

This entropy can be varied continuously to achieve all values in the maximal range 0SA,1ln(2)0\leq S_{A,1}\leq\ln{2}, by varying 0q10\leq q_{1}\leq\infty, or equivalently h1J1-\infty\leq\frac{h_{1}}{J_{1}}\leq\infty. We see that by varying the physical parameters of our model we can achieve all degrees of pairwise entanglement between the two spins.

Refer to caption
Figure 1: The variation of the Renyi entropy, SA,1(α)S_{A,1}^{(\alpha)} for states given in (2) as a function of their deformation parameter q1q_{1}, for a range of fixed values of α\alpha. The Renyi entropy takes maximal value SA,1(α)=ln(2)S_{A,1}^{(\alpha)}=\ln{2} when the deformation parameter q1=1,q_{1}=1, for all α\alpha, and is unchanged under the transformation, h1h1h_{1}\rightarrow-h_{1}, such that q11q1q_{1}\rightarrow\frac{1}{q_{1}}, reflecting a symmetry of the Hamiltonian (1).

II.2 2N2N Spin Hamiltonian

The simple two-spin Hamiltonian presented above is the basis on which we construct our general model for a chain of any even number of spins. We now consider a chain of 2N2N spin-12\frac{1}{2} particles with the following Hamiltonian

=i=1Nhi(σizσiz)+J1(σ1xσ1x+σ1yσ1y)+i=2NJi(σixσ(i1)x+σiyσ(i1)y+σi1xσix+σi1yσiy).\mathcal{H}=\sum_{i=1}^{N}h_{i}\left(\sigma_{-i}^{z}-\sigma_{i}^{z}\right)+J_{1}\left(\sigma_{-1}^{x}\sigma_{1}^{x}+\sigma_{-1}^{y}\sigma_{1}^{y}\right)\\ +\sum_{i=2}^{N}J_{i}\left(\sigma_{-i}^{x}\sigma_{-(i-1)}^{x}+\sigma_{-i}^{y}\sigma_{-(i-1)}^{y}+\sigma_{i-1}^{x}\sigma_{i}^{x}+\sigma_{i-1}^{y}\sigma_{i}^{y}\right). (8)

We have introduced the site labelling {N,(N1),,2,1,1,2,,N1,N}\{-N,-(N-1),\dots,-2,-1,1,2,\dots,N-1,N\} such that sites i-i and ii are equidistant from a central bipartition of the chain, as shown in Figure 2.

Refer to caption
Figure 2: The qq-deformed spin model for a chain of 2N2N sites. The blue lines represent the XX coupling terms, JiJ_{i}, and the red arrows represent the magnitude and direction of the transverse magnetic field, hih_{i}. The magnitude of both the coupling and transverse field are symmetric about the centre of the chain, with decreasing strength moving outwards.

In order to find the ground state of our model we have used the Real-Space Renormalization Group approach as first introduced by Ma and Dasgupta in [41] and later developed by Fisher with the application of the method to the Random Transverse Field Ising Chain [42]. This approach allows us to consider the ground state properties of random quantum chains by iteratively decimating the degrees of freedom with highest energy in order to derive an overall effective low-energy model. We start by first briefly reviewing this method with reference to the known results of the hi0h_{i}\rightarrow 0 limit of our model.

II.2.1 XX Model Renormalization Group

In the limit, hi=0h_{i}=0, our Hamiltonian (8) is equivalent to that of the inhomogeneous XX model acting on a chain of 2N2N spins

HXX=i=12NJi(σixσi+1x+σiyσi+1y),H_{XX}=\sum_{i=1}^{2N}J_{i}\left(\sigma_{i}^{x}\sigma_{i+1}^{x}+\sigma_{i}^{y}\sigma_{i+1}^{y}\right), (9)

where we have re-adopted the standard site labelling {1,2,,2N1,2N}\{1,2,\dots,2N-1,2N\}. Using the Renormalization Group (RG) approach for some random coupling profile, the highest energy term such that JiJi1,Ji+1J_{i}\gg J_{i-1},J_{i+1}, is identified and diagonalised independently of the rest of the chain. To zeroth-order in perturbation theory, the ground state of the system is then

|ψ=|ψj<i|ψi|ψj>i,\ket{\psi}=\ket{\psi_{j<i}}\otimes\ket{\psi^{-}_{i}}\otimes\ket{\psi_{j>i}}, (10)

where |ψi=12(|i,i+1|i,i+1)\ket{\psi^{-}_{i}}=\frac{1}{\sqrt{2}}(\ket{\uparrow\downarrow}_{i,i+1}-\ket{\downarrow\uparrow}_{i,i+1}) is the maximally entangled singlet ground state of the two-site XX model and |ψj<i\ket{\psi_{j<i}}, |ψj>i\ket{\psi_{j>i}} refer to the state of the spins to the left and right of the singlet, respectively. To compute higher order corrections to the ground state of our system we initial consider the spins ii and i+1i+1 to be ‘frozen’ into this singlet state. Then we employ perturbation theory to find the effect induced by quantum fluctuations on the neighbouring spins, as shown in [12]. It is found that an effective coupling arises between sites i1i-1 and i+2i+2 of strength

J~i1,i+2=Ji1Ji+1Ji.\tilde{J}_{i-1,i+2}=\frac{J_{i-1}J_{i+1}}{J_{i}}. (11)

In this way the coupling between sites ii and i+1i+1 is replaced by effective longer range interaction that captures the low-energy properties of the model. For a random coupling profile, successive iterations of this procedure yield a ‘random singlet phase’, as singlets form between the pairs of spins most strongly coupled after each decimation. In [12] Vitagliano, Riera and Latorre demonstrated how a coupling profile that decays exponentially away from the centre of the chain produces a special form of ground state known as the ‘concentric singlet phase’. This ground state is also known as the ‘rainbow state’, due to it’s distinctive structure of a series of singlets symmetrically distributed around the centre of the chain. For any given bipartition, the entanglement entropy is directly proportional to the number of singlets ‘cut’ by the bipartition. Thus, for such a coupling profile, the area law of entanglement entropy is maximally violated.

II.2.2 qq-Deformed Model Renormalization Group

We now apply the Real-Space RG approach to the generalised model defined in (8). In the limit J1,h1J2,h2J_{1},h_{1}\gg J_{2},h_{2}, this yields the ground state

|ψ=|ψi<1|ψ1|ψi>1,\ket{\psi}=\ket{\psi_{i<-1}}\otimes\ket{\psi_{1}}\otimes\ket{\psi_{i>1}}, (12)

to zeroth-order in perturbation theory, where |ψ1\ket{\psi_{1}} is the q1q_{1}-deformed singlet as defined in equation (4). To compute corrections to the ground state at higher orders, second-order perturbation theory is used, as illustrated in Figure 3 (see also Appendix A). We derive an effective Hamiltonian of the form (1) acting between sites 2-2 and 22 with a renormalized coupling

J2~=4J22[2]q12J1,\tilde{J_{2}}=\frac{4J_{2}^{2}}{[2]_{q_{1}}^{2}J_{1}}, (13)

and transverse field terms

h~2=h22(q11q1)J22[2]q12J1.\tilde{h}_{2}=h_{2}-\frac{2\left(q_{1}-\frac{1}{q_{1}}\right)J_{2}^{2}}{[2]_{q_{1}}^{2}J_{1}}. (14)

In the case that J2~,h~2J3,h3\tilde{J_{2}},\tilde{h}_{2}\gg J_{3},h_{3} this effective Hamiltonian can be diagonalised to yield an additional q2q_{2}-deformed singlet, |ψ2\ket{\psi_{2}}, between sites 2-2 and 22, where q2=eγ2,q_{2}=e^{\gamma_{2}}, sinhγ2=h~2J2~\sinh{\gamma_{2}}=\frac{\tilde{h}_{2}}{\tilde{J_{2}}}.

Refer to caption
Figure 3: The Real-Space RG procedure. (a) Our model (8) acting on a chain of four spins. For J1,h1J2,h2J_{1},h_{1}\gg J_{2},h_{2} perturbation theory yields a qq-deformed singlet (4) between the central two spins. (b) These spins are integrated out and an effective Hamiltonian of the form (1) is found to act between sites 2-2 and 22 with renormalized coupling J2~\tilde{J_{2}} and transverse field h~2\tilde{h}_{2}. (c) Diagonalization of this effective Hamiltonian yields the ground state |ψ=|ψ1|ψ2\ket{\psi}=\ket{\psi_{1}}\otimes\ket{\psi_{2}}. The difference in colour of the bonds between the two pairs indicates the difference in correlations that can be achieved by appropriately tuning J1,J2,h1J_{1},J_{2},h_{1} and h2h_{2}.

If the couplings throughout the chain are selected such that Ji~,h~iJi+1,hi+1\tilde{J_{i}},\tilde{h}_{i}\gg J_{i+1},h_{i+1}, then repeated iterations of this renormalization process will eventually yield the overall ground state

|ψ=|ψ1|ψ2|ψN,\ket{\psi}=\ket{\psi_{1}}\otimes\ket{\psi_{2}}\otimes\dots\otimes\ket{\psi_{N}}, (15)

where

|ψi=1[2]qi(qi12|i,iqi12|i,i),\ket{\psi_{i}}=\frac{1}{\sqrt{[2]_{q_{i}}}}\left(q_{i}^{-\frac{1}{2}}\ket{\uparrow\downarrow}_{-i,i}-q_{i}^{\frac{1}{2}}\ket{\downarrow\uparrow}_{-i,i}\right), (16)

and for i>1i>1

qi=eγi with sinhγi=h~iJi~.q_{i}=e^{\gamma_{i}}\text{ with }\sinh{\gamma_{i}}=\frac{\tilde{h}_{i}}{\tilde{J_{i}}}. (17)

The renormalized coupling and transverse field parameters for the effective Hamiltonian between spins i-i and ii are given by the recursive expressions

Ji~=4Ji2[2]qi12J~i1,\tilde{J_{i}}=\frac{4J_{i}^{2}}{[2]_{q_{i-1}}^{2}\tilde{J}_{i-1}}, (18)
h~i=hi2(qi11qi1)Ji2[2]qi12J~i1.\tilde{h}_{i}=h_{i}-\frac{2\left(q_{i-1}-\frac{1}{q_{i-1}}\right)J_{i}^{2}}{[2]_{q_{i-1}}^{2}\tilde{J}_{i-1}}. (19)

From equations (18) and (19), we see that the expressions for Ji~\tilde{J_{i}} and h~i\tilde{h}_{i} are dependent on all previous J~j<i\tilde{J}_{j<i}, h~j<i\tilde{h}_{j<i}. By fixing all previous i1i-1 values, it is always possible to vary the associated physical parameters JiJ_{i} and hih_{i} such as to achieve any 1qi1\leq q_{i}\leq\infty. In this way, we will show that the deformation of each qq-singlet can be individually tuned to achieve any degree of pairwise entanglement between a given pair of spins.

III Entanglement Properties of the qq-Deformed Rainbow

The ground state (15) of our Hamiltonian (8) has a tensor product form. Subsequently, the reduced density matrix across a central bipartition admits the tensor product decomposition

ρA=ρ1ρ2ρN,\rho_{A}=\rho_{1}\otimes\rho_{2}\otimes\dots\otimes\rho_{N}, (20)

where each ρi\rho_{i} is diagonal, given by

ρi=(11+qi200qi21+qi2).\rho_{i}=\begin{pmatrix}\frac{1}{1+q_{i}^{2}}&0\\ 0&\frac{q_{i}^{2}}{1+q_{i}^{2}}\end{pmatrix}. (21)

This decomposition yields simple expressions for many of the entanglement properties of the qq-deformed rainbow, as we will see in the following.

III.1 Renyi and von Neumann entropies

Using the reduced density matrix tensor product decomposition we derive the form of the Renyi entropy of order α\alpha of the ground state (15) across a central bipartition

SA(α)=11αi=1Nln(1+qi2α(1+qi2)α),α>0,α1.S_{A}^{(\alpha)}=\frac{1}{1-\alpha}\sum_{i=1}^{N}\ln{\frac{1+q_{i}^{2\alpha}}{(1+q_{i}^{2})^{\alpha}}},\hskip 8.5359pt\alpha>0,\alpha\neq 1. (22)

In the limit α1\alpha\rightarrow 1 we obtain an expression for the von Neumann entropy of the ground state

SA=i=1N[ln((1+qi2))qi21+qi2ln(qi2)].S_{A}=-\sum_{i=1}^{N}\left[\ln{(1+q_{i}^{2})}-\frac{q_{i}^{2}}{1+q_{i}^{2}}\ln{q_{i}^{2}}\right]. (23)

In Section II.1 we found the von Neumann entropy, SA,1S_{A,1}, of a single pair of spins as a function of the deformation parameter q1q_{1}, as given by (6). By extending this definition to that of the von Neumann entropy of the state |ψi\ket{\psi_{i}} between spins i-i and ii

SA,i=ln((1+qi2))qi21+qi2ln(qi2),S_{A,i}=\ln{(1+q_{i}^{2})}-\frac{q_{i}^{2}}{1+q_{i}^{2}}\ln{q_{i}^{2}}, (24)

it is clear that the total von Neumann entropy is a sum of the individual von Neumann entropies of each concentric pair of spins on the chain. This is also true for the Renyi entropy, and is a natural consequence of the tensor product form of the reduced density matrix. By independently varying each qiq_{i}, we can therefore achieve all degrees of entanglement in the allowed maximal range 0SANln(2)0\leq S_{A}\leq N\ln{2}.

III.2 Entanglement Spectrum

The entanglement spectrum was introduced by Li and Haldane [43] as an alternative entanglement measure that aimed to capture a complete representation of the entanglement between two subsystems [44]. The values of the spectrum, EiE_{i}, are related to the eigenvalues of the reduced density matrix, λi\lambda_{i}, via

λi=eEi.\lambda_{i}=e^{-E_{i}}. (25)

The exponential relationship means that the dominant quantum correlations depend predominantly on the ‘lowest’ part of the entanglement spectrum.

The entanglement spectrum reflects many of the physical properties of the system [45, 46, 47, 48, 49] and serves as a fingerprint of topological order [50, 51, 52]. For any non-interacting model, Wick’s theorem shows that the spectrum can be constructed from a set of single-particle entanglement energies as

Ejf(ϵ)=E0+i=1Nni(j)ϵi,E^{f}_{j}(\epsilon)=E_{0}+\sum_{i=1}^{N}n_{i}(j)\epsilon_{i}, (26)

where E0E_{0} is a normalization constant and each nj={0,1}n_{j}=\{0,1\} [53].

For our qq-deformed rainbow, we find that

E0=i=1Nln((1+qi2)),E_{0}=\sum_{i=1}^{N}\ln{(1+q_{i}^{2})}, (27)

and

ϵi=ln(qi2).\epsilon_{i}=-\ln{q_{i}^{2}}. (28)

Hence, the deformation parameters, qiq_{i}, of the qq-deformed singlets directly determine the single-particle entanglement energies. As each qiq_{i} can take any value in the range 0qi0\leq q_{i}\leq\infty, each ϵi\epsilon_{i} can be individually tuned to take any value ϵi-\infty\leq\epsilon_{i}\leq\infty.

Refer to caption
Figure 4: The values of h2h_{2} required to generate any 0ϵ2100\leq\epsilon_{2}\leq 10 for fixed J1=h1=1J_{1}=h_{1}=1, J2=0.01J_{2}=0.01 (ϵ1=2sinh1(1)\epsilon_{1}=-2\sinh^{-1}{(1)}). Any desired value of ϵ2\epsilon_{2} in this range can be obtained by selecting the corresponding value of h2h_{2}.

By combining (17) and (28) we derive the simple relationship

γi=ϵi2.\gamma_{i}=-\frac{\epsilon_{i}}{2}. (29)

This in turn yields an expression for the required ratio of the renormalized parameters for a given pair in order to produce a specific desired single-particle entanglement energy

h~iJi~=sinh(ϵi2).\frac{\tilde{h}_{i}}{\tilde{J_{i}}}=-\sinh{\left(\frac{\epsilon_{i}}{2}\right)}. (30)

As a result, each single particle energy of the entanglement spectrum can be directly obtained by appropriately tuning a single effective magnetic field. In Appendix B we expand these expressions to derive closed forms for the required ratio of the physical coupling parameters. In Figure 4 the dependence of ϵ2\epsilon_{2} on h2h_{2} for fixed J1,h1J_{1},h_{1} and J2J_{2} is illustrated. For the shown range, any desired ϵ2\epsilon_{2} can be simulated by simply reading off the corresponding value of h2h_{2}. In this way, by fixing all previous i1i-1 single-particle entanglement energies, ϵi\epsilon_{i} can be tuned to any desired value by appropriately varying hih_{i}.

IV Fidelity Optimisation

In the previous Section, we have demonstrated how controlled variation of the parameters of our model in the strong inhomogeneity limit Ji~,h~iJi+1,hi+1\tilde{J_{i}},\tilde{h}_{i}\gg J_{i+1},h_{i+1} allows for the generation of any arbitrary pattern of correlations given in terms of the entanglement entropy (23) or the single-particle entanglement energies (30). In this Section we present how the parameters of our model can be chosen such that the fidelity is maximised for any desired entanglement profile. In quantum information theory, fidelity is a measure of the ‘closeness’ of two quantum states, |ψA\ket{\psi_{A}} and |ψB\ket{\psi_{B}}, given by the squared overlap, |ψA|ψB|2\absolutevalue{\bra{\psi_{A}}\ket{\psi_{B}}}^{2} [54]. To optimise the choice of parameters for any desired correlation profile, we consider the variation of the fidelity between the exact ground state of our model and the qq-deformed rainbow in the case N=4N=4.

IV.1 Optimising h2h_{2}

Refer to caption
Figure 5: Variation of the ground state fidelity with the entanglement entropy of the outer pair for different fixed values of h1h_{1} with J1=1J_{1}=1 and J2=0.1J_{2}=0.1. The grey line shows an example of a desired outer entanglement entropy, SA,2=0.5S_{A,2}=0.5. The two intersections with each curve for h1>0h_{1}>0 indicate two possible values of h2h_{2} to generate the desired SA,2S_{A,2} with a distinct difference in fidelity. This choice can be used to optimise the accuracy of our model.

In Section II.1, we noted that a symmetry of our two-site Hamiltonian (1) results in the preservation of the von Neumann entropy, SA,1S_{A,1}, under the transformation h1h1h_{1}\rightarrow-h_{1}. Here, we will show that although SA,2S_{A,2} possesses a similar symmetry under the transformation h~2h~2\tilde{h}_{2}\rightarrow-\tilde{h}_{2}, one of these values will yield a significantly higher fidelity than the other corresponding to the choice of sign of h1J1\frac{h_{1}}{J_{1}}.

In Figure 5 we plot the fidelity between the qq-deformed rainbow and the exact ground state of (8) as a function of the entanglement entropy between sites 2-2 and 22 for a range of constant values of h1h_{1}. For each curve J1,h1J_{1},h_{1} and J2J_{2} are fixed such that SA,2S_{A,2} is a function of h2h_{2}. We see that for any desired value of SA,2S_{A,2}, for example SA,2=0.5S_{A,2}=0.5 as indicated by the vertical grey line, the two intersections with each curve indicate two values of h2h_{2} that correspond to the same degree of entanglement, but with a distinct difference in fidelity. As described, these two solutions arise due to the natural symmetry of the entanglement entropy about the value of h2h_{2} yielding maximal entanglement between sites 2-2 and 22. To find the value h2maxh_{2}^{\text{max}} that maximises SA,2S_{A,2} we set h~2=0\tilde{h}_{2}=0 in equation (14) and obtain

h2max=2(q11q1)J22[2]q12J1.h_{2}^{\text{max}}=\frac{2\left(q_{1}-\frac{1}{q_{1}}\right)J_{2}^{2}}{[2]_{q_{1}}^{2}J_{1}}. (31)

The symmetry of the entanglement entropy SA,2S_{A,2} about h2maxh_{2}^{\text{max}} is shown in Figure 6(a) for the case J1=h1=1J_{1}=h_{1}=1, J2=0.1J_{2}=0.1. By mapping these values onto the plot of fidelity with SA,2S_{A,2} as shown in Figure 6(b), we see that we have a ‘high fidelity branch’ corresponding to h2h2maxh_{2}\geq h_{2}^{\text{max}} and a ‘low fidelity branch’ for h2h2maxh_{2}\leq h_{2}^{\text{max}}. For any desired value of SA,2S_{A,2}, the fidelity is clearly maximised by choosing the appropriate value of h2h2maxh_{2}\geq h_{2}^{\text{max}}. In contrast, if h1J1\frac{h_{1}}{J_{1}} is negative as shown in Figure 6(c) and (d), the opposite is true, and the fidelity is maximised by selecting the value of h2h_{2} from the branch h2h2maxh_{2}\leq h_{2}^{\text{max}}. In this way, for fixed couplings J1J_{1} and J2J_{2}, the direction of the magnetic fields applied to sites i=1,1i=-1,1 dictate the magnitude and direction of the magnetic field that should be applied to sites i=2,2i=-2,2 in order to maximise the accuracy of our model.

Refer to caption
Figure 6: (a) Variation of the entanglement entropy of the outer pair with h2h_{2} for J1=h1=1J_{1}=h_{1}=1 and J2=0.1J_{2}=0.1. (b) The corresponding variation of the ground state fidelity with the entanglement entropy for both the values less than and greater than h2maxh_{2}^{\text{max}}. The higher fidelity branch corresponds to the values h2h2maxh_{2}\geq h_{2}^{\text{max}}. (c) Variation of the entanglement entropy of the outer pair with h2h_{2}, now for J1=1J_{1}=1, J2=0.1J_{2}=0.1 and h1=1h_{1}=-1. (d) The corresponding variation of the ground state fidelity with the entanglement entropy for both the values less than and greater than h2maxh_{2}^{\text{max}}. The higher fidelity branch now corresponds to the values h2h2maxh_{2}\leq h_{2}^{\text{max}}. On all four subfigures the solid grey line serves to illustrate this fidelity optimisation for the specific case SA,2=0.5S_{A,2}=0.5.

IV.2 Optimising Order of Pairs

Our system has a symmetry with respect to which pair i,ii,-i of spins is used to tune a certain single particle entanglement energy ϵk\epsilon_{k}. We can use this freedom, in conjunction with the optimisation procedure of the previous Subsection to optimise the overall fidelity of our chain simulator. To proceed, we adopt the appropriately restricted range of h2h2maxh_{2}\geq h_{2}^{\text{max}} that maximises the fidelity of two pairs of spins. We then consider the variation of the fidelity with h2h_{2} for a range of fixed values of h1h_{1} as shown in Figure 7(a). Here h1J1>0\frac{h_{1}}{J_{1}}>0 for each curve such that we have selected the values h2h2maxh_{2}\geq h_{2}^{\text{max}}. We first observe that for each fixed value of h1h_{1}, as SA,2S_{A,2} increases, the fidelity decreases. This result is more notable for low values of h1h_{1}, such that the combination of parameters with lowest fidelity corresponds to the reproduction of the rainbow state with h1=h2=0h_{1}=h_{2}=0. Hence, our model is best at accurately producing lower degrees of entanglement between the concentric pairs of sites.

For fixed J1J_{1}, a larger magnitude of h1h_{1} coresponds to a lower value of SA,1S_{A,1}. Figure 7(a) therefore also shows that as the value of h1h_{1} increases and SA,1S_{A,1} decreases, the fidelity with which any desired SA,2S_{A,2} can be achieved increases. Consider the case in which we want to use our model to generate a given pair of two-site von Neumann enanglement entropies, for example, SA,i=0.2S_{A,i}=0.2 and SA,j=0.6S_{A,j}=0.6. Our simulator has the freedom in the choice i=1,j=2i=1,j=2 or i=2,j=1i=2,j=1. We will employ this freedom to choose the combination that maximises the fidelity. In Figure 7(b) we plot the two curves corresponding to SA,1=0.2S_{A,1}=0.2, and SA,1=0.6S_{A,1}=0.6. It is clear from this plot that the fidelity is always maximum by choosing the parameters such that SA,1=0.2,SA,2=0.6S_{A,1}=0.2,S_{A,2}=0.6. In general it is always true that the fidelity is maximised by ordering the pairs such that SA,iSA,i+1S_{A,i}\leq S_{A,i+1}. Figure 8 further illustrates this with a direct comparison of the fidelity with the degree of entanglement between one pair when the other is maximally entangled. For all values of SA,iS_{A,i}, we observe that the fidelity is maximised when the maximally entangled state lies between sites 2-2 and 22.

Refer to caption
Figure 7: (a) The variation of the fidelity with SA,2S_{A,2} for a range of values of h1h_{1} and fixed J1=1J_{1}=1, J2=0.1J_{2}=0.1. We observe that always the fidelity decreases as SA,2S_{A,2} increases. For two curves with different value of h1h_{1}, it is observed that all values of SA,2S_{A,2} can be produced with a higher fidelity by the curve with a higher value of h1h_{1} or equivalently a lower value of SA,1S_{A,1}. The implications of this on producing some desired set of von Neumann entropies are examined further in (b). Here the dashed lines serve to illustrate the higher value of fidelity achieved by choosing h1h_{1} and h2h_{2} to obtain SA,1=0.2,SA,2=0.6S_{A,1}=0.2,S_{A,2}=0.6 as opposed to SA,1=0.6,SA,2=0.2S_{A,1}=0.6,S_{A,2}=0.2. In general, the fidelity is optimised by selecting the parameters of our model such that SA,iSA,i+1S_{A,i}\leq S_{A,i+1}.

By combining equations (24) and (28), we see that the condition SA,iSA,i+1S_{A,i}\leq S_{A,i+1} is equivalent to |ϵi||ϵi+1|\absolutevalue{\epsilon_{i}}\geq\absolutevalue{\epsilon_{i+1}}. For some desired set of single-particle entanglement energies, {ϵi}\{\epsilon_{i}\}, our model allows for complete freedom in assigning which pair of sites corresponds to a given energy. In implementing our model we therefore choose to tune the parameters such that the magnitude of the single-particle energy generated by sites i-i and ii decreases with increasing ii in order to optimise the fidelity.

Refer to caption
Figure 8: The fidelity of the four-site qq-deformed rainbow and the exact ground state of our model when one pair is maximally entangled and the entanglement entropy of the other is varied (J1=1,J2=0.1J_{1}=1,J_{2}=0.1). For every combination of entanglement entropies, the fidelity is maximised by choosing our parameters such that the maximally entangled pair is between sites 2-2 and 22.

V Special Cases

We have shown how the tuning of the parameters of our model allows for the generation of any arbitrary set of single-particle entanglement energies. In this section we highlight two interesting applications: the case in which all deformation parameters are equal, and the reproduction of the single-particle entanglement energies for the ‘prime number spectrum’ introduced below.

V.1 The q1=q2==qN=qq_{1}=q_{2}=\dots=q_{N}=q Case

In the rainbow state model, the ground state is a tensor product of concentric maximally entangled singlets, or in the language of our model, qi=1q_{i}=1, for all ii. Here, we show how the parameters of our model can be chosen such that all deformation parameters take the same value, qi=qq_{i}=q, for some chosen qq in the allowed range 0<q<0<q<\infty. In this way, each concentric pair on our chain shares the same degree of pairwise entanglement, and all single-particle entanglement energies are equal.

We have defined q1=esinh1(h1J1)q_{1}=e^{\sinh^{-1}\left(\frac{h_{1}}{J_{1}}\right)} and qi>1=esinh1(h~iJi~)q_{i>1}=e^{\sinh^{-1}\left(\frac{\tilde{h}_{i}}{\tilde{J_{i}}}\right)}, such that the condition q1=qih1J1=h~iJi~q_{1}=q_{i}\implies\frac{h_{1}}{J_{1}}=\frac{\tilde{h}_{i}}{\tilde{J_{i}}}. Re-arranging equation (4) and setting q1=qq_{1}=q yields

h1J1=12(q1q),\frac{h_{1}}{J_{1}}=\frac{1}{2}\left(q-\frac{1}{q}\right), (32)

for some desired q>0q>0.

For all other pairs of sites the relations for the renormalised couplings must be used. For example. by dividing equation (14) by equation (13) and equating with (32) we obtain

h2=2J22h1(1q2)2(1+q2)2.h_{2}=\frac{2J_{2}^{2}}{h_{1}}\frac{\left(1-q^{2}\right)^{2}}{\left(1+q^{2}\right)^{2}}. (33)

For any fixed value of J2J_{2} this relation can be easily implemented to find the required transverse field parameter to produce some desired q>0q>0.

In the same way, the ratio of equations (18) and (19) can be equated with (32) in order to obtain the general formula

hi=4Ji2hi1(1q2)2(1+q2)2,i>2h_{i}=\frac{4J_{i}^{2}}{h_{i-1}}\frac{\left(1-q^{2}\right)^{2}}{\left(1+q^{2}\right)^{2}},\hskip 5.69046pti>2 (34)

By iterating through and systematically determining each successive value of the required transverse field for some fixed coupling profile, these relations allow us to produce a one-dimensional chain in which each concentric pair shares the same degree of pairwise entanglement. In Figures 9(a) and (b) it is shown how all values of 1q101\leq q\leq 10 and the corresponding entanglement entropies for the case N=4N=4 can be produced with a very high level of fidelity. For just J1=1,J2=0.01J_{1}=1,J_{2}=0.01 the error is of the order of 10410^{-4}.

Refer to caption
Figure 9: (a) The variation of the ground state fidelity for 1q101\leq q\leq 10 in the special case q1=q2=qq_{1}=q_{2}=q for N=4N=4. Here J1=1,J2=0.01J_{1}=1,J_{2}=0.01 (b) The corresponding variation of the fidelity with the associated range of equal von Neumann entanglement entropies across both pairs. All values in the range shown can be produced with a very high level of fidelity.

V.2 Prime Number Spectrum

Prime numbers play an important role in number theory. The Fundamental Theorem of Arithmetics [55] states that every natural number greater than one can be uniquely factorised as a product of prime numbers

N=2n23n3pnp,N=2^{n_{2}}3^{n_{3}}\dots p^{n_{p}}\dots, (35)

where pp is a prime and npn_{p} counts the number of times that pp appears in the factorisation of NN. In this way, prime numbers can be thought of as the building blocks of all natural numbers.

Let us introduce the Moebius function, μ(n)\mu(n):

μ(n)={1,n=1,(1)r,n=p1pr,0,p,p2|n,\mu(n)=\begin{cases}1,&n=1,\\ (-1)^{r},&n=p_{1}\dots p_{r},\\ 0,&\exists p,p^{2}|n,\end{cases} (36)

where pp are prime numbers. The symbol p2|np^{2}|n means that p2p^{2} divides nn. A square free integer is an integer whose factorization into products of primes does not contain any square of a prime numbers. μ(n)\mu(n) is therefore non-vanishing only on square free integers and its value is +1+1 if it contains an even number of primes and 1-1 if it contains an odd number of primes. In this way, the function μ\mu is a sort of Fermi statistics if we think of the primes as being fermions.

Let us now consider an entanglement spectrum of the form

λk=AF|μ(k)|ks,AF,s>0,k=1,,.\lambda_{k}=\frac{A_{F}\absolutevalue{\mu(k)}}{k^{s}},\hskip 5.69046ptA_{F},s>0,\hskip 2.84544ptk=1,\dots,\infty. (37)

The normalization of the eigenvalues implies that

1=k=1λk=AFp(1+ps)=AFζ(s)ζ(2s),1=\sum_{k=1}^{\infty}\lambda_{k}=A_{F}\prod_{p}(1+p^{-s})=A_{F}\frac{\zeta(s)}{\zeta(2s)}, (38)

where we have used the Euler product formula

ζ(s)=p11ps,Re(s)>1.\zeta(s)=\prod_{p}\frac{1}{1-p^{-s}},\hskip 5.69046pt\text{Re}(s)>1. (39)

Using equation (25), the entanglement energies for this spectrum are given by

Ek=ln(λk)=ln(AF)+sln(k).E_{k}=-\ln{\lambda_{k}}=-\ln{A_{F}}+s\ln{k}. (40)

Where kk is any square free integer. We equate this expression with that of the spectrum of a free fermionic system

ln(AF)+sln(k)=E0+i=1Nni(k)ϵi.-\ln{A_{F}}+s\ln{k}=E_{0}+\sum_{i=1}^{N}n_{i}(k)\epsilon_{i}. (41)

If kk is a square free integer then from the Fundamental Theorem of Arithmetics one has

k=2n23n3pnp,ni=0,1,k=2^{n_{2}}3^{n_{3}}\dots p^{n_{p}}\dots,\hskip 8.5359ptn_{i}=0,1, (42)

such that taking the logarithm of (42) yields

ln(k)=p:primenpln(p),np=0,1.\ln{k}=\sum_{p:prime}n_{p}\ln{p},\hskip 8.5359ptn_{p}=0,1. (43)

Hence, equation (41) is solved by

E0=ln(AF)=ζ(s)ζ(2s),E_{0}=-\ln{A_{F}}=\frac{\zeta(s)}{\zeta(2s)}, (44)
ϵp=sln(p).\epsilon_{p}=s\ln{p}. (45)

The parameter ss can be thought of as an entanglement temperature since it is common to all eigenenergies. The relation (45) has also been considered in [56, 57] with ln(p)\ln{p} being the single-particle energies of the primon gas. The partition function of this gas is related to the Riemann zeta function, ζ(s)\zeta(s). In recent work, a prime number eigenvalue spectrum has also been experimentally realised by application of holographic optical traps [58], in agreement with previous theoretical results [59].

In Section IV.2, we saw that the highest ground state fidelity is achieved by fixing our parameters {hi}\{h_{i}\} and {Ji}\{J_{i}\} such that |ϵi||ϵi+1|\absolutevalue{\epsilon_{i}}\geq\absolutevalue{\epsilon_{i+1}}. Thus, in order for our model to most accurately reproduce this prime number spectrum, we choose ϵi=sln(pi)\epsilon_{i}=s\ln{p_{i}} such that pi>pi+1p_{i}>p_{i+1}. The required values of the set {hi}\{h_{i}\}, for some fixed coupling profile {Ji}\{J_{i}\}, can then be simply read off from equations (67), (68) and (69) in the Appendices.

VI Conclusions

In summary, we have introduced a spin chain that can produce arbitrary ground state free-particle correlations across a given bipartition. Our scheme is a generalisation of the rainbow states of concentric maximally entangled singlets to the case of concentric pairs, each one with arbitrary entanglement. The degree of entanglement is easily tuned by appropriately choosing the magnitude of local magnetic fields. The entanglement across the bipartition can be parametrised in terms of single particle energies of the entanglement spectra. We find that for a fixed coupling profile these energies are simple functions of the magnetic fields, thus providing direct accessibility and tunability.

To test the validity and applicability of our method we compare the fidelity of the predicted theoretical model with the exact diagonalisation of the spin system. The employed perturbation method has a symmetry in terms of the ordering of the concentric entangled states. By taking advantage of this symmetry we find the optimal order of magnetic fields that gives the best fidelities. Finally, we apply our method to two case scenarios. First, we consider the homogeneous case of concentric pairs with the same entanglement. Second, we consider the case of single particle energies of the entanglement spectra that are parametrised by prime numbers. This model is inspired by the similarity between the decomposition of free-system entanglement spectra in terms of single particle energies and the decomposition of integers in terms of prime numbers. In recent experimental work, holographic techniques have been developed allowing for the tuning of the energy spectrum of the single-particle Schrödinger equation [58]. Notably a ‘prime number quantum potential’, VN(x)V_{N}(x), can be applied such that the single-particle Schrödinger equation has the lowest NN prime numbers as eigenvalues. These techniques demonstrate an interesting procedure for the reproduction of arbitrary sequences of integers as energy spectra with possible applicability to this work.

Our methodology can have a direct application in quantum technologies, whenever a very specific pattern of quantum correlations is required [60, 61, 62]. It can also simulate quantum phases of matter that require specific ground state correlations across a bipartition. Finally, our approach opens the way to investigate inhomogeneous spin chains in the presence of disordered magnetic fields, which is physically a common scenario, thus generalising previous approaches [63, 17].

Acknowledgements.
We would like to thank Gabriel Matos and Andrew Hallam for inspiring conversations. L.B. acknowledges support from EPSRC Grant No. EP/T517860/1. This work was also in part supported by EPSRC Grant No. EP/R020612/1. G.S. acknowledges financial support through the Spanish MINECO grant PID2021-127726NB-I00, the Comunidad de Madrid Grant No. S2018/TCS-4342, the Centro de Excelencia Severo Ochoa Program SEV-2016-0597 and the CSIC Research Platform on Quantum Technologies PTI-001.

Appendix A Four Site Perturbation Theory

In order to illustrate the Real-Space RG approach, we apply perturbation theory to our Hamiltonian (8) restricted to a chain of four sites

H=H1+λV,H=H_{1}+\lambda V, (46)

where

H1=J1(σ1xσ1x+σ1yσ1y)+h1(σ1zσ1z),H_{1}=J_{1}(\sigma_{-1}^{x}\sigma_{1}^{x}+\sigma_{-1}^{y}\sigma_{1}^{y})+h_{1}(\sigma_{-1}^{z}-\sigma_{1}^{z}), (47)

and

V=J2(σ2xσ1x+σ2yσ1y+σ1xσ2x+σ1yσ2y)+h2(σ2zσ2z).V=J_{2}^{\prime}(\sigma_{-2}^{x}\sigma_{-1}^{x}+\sigma_{-2}^{y}\sigma_{-1}^{y}+\sigma_{1}^{x}\sigma_{2}^{x}+\sigma_{1}^{y}\sigma_{2}^{y})+h_{2}^{\prime}(\sigma_{-2}^{z}-\sigma_{2}^{z}). (48)

Here the couplings J2=λJ2J_{2}=\lambda J_{2}^{\prime} and h2=λh2h_{2}=\lambda h_{2}^{\prime}, such that for any λ1\lambda\ll 1, the perturbative condition J2,h2J1,h1J_{2},h_{2}\ll J_{1},h_{1} is ensured.

On two sites, H1H_{1} has the following eigenstates

|ψ=1[2]q1(q112|q112|),\ket{\psi^{-}}=\frac{1}{\sqrt{[2]_{q_{1}}}}\left(q_{1}^{-\frac{1}{2}}\ket{\uparrow\downarrow}-q_{1}^{\frac{1}{2}}\ket{\downarrow\uparrow}\right), (49)
|ψ0=|,\ket{\psi^{0}}=\ket{\uparrow\uparrow}, (50)
|ψ1=|,\ket{\psi^{1}}=\ket{\downarrow\downarrow}, (51)
|ψ+=1[2]q1(q112|+q112|),\ket{\psi^{+}}=\frac{1}{\sqrt{[2]_{q_{1}}}}\left(q_{1}^{\frac{1}{2}}\ket{\uparrow\downarrow}+q_{1}^{-\frac{1}{2}}\ket{\downarrow\uparrow}\right), (52)

with eigenenergies E1=[2]q1J1,Es=0,Et=0E_{1}=-[2]_{q_{1}}J_{1},E_{s}=0,E_{t}=0 and Ek=+[2]q1J1E_{k}=+[2]_{q_{1}}J_{1} respectively, and q1q_{1} as previously defined in equation (4).

When extended to a chain of four spins, the ground state subspace of H1H_{1} becomes four-fold degenerate. We represent this subspace with the basis vectors: {|m}={|m1,|m2,|m3,|m4}\{\ket{m}\}=\{\ket{m_{1}},\ket{m_{2}},\ket{m_{3}},\ket{m_{4}}\} ={|2|ψ1,1|2=\{\ket{\uparrow}_{-2}\ket{\psi^{-}}_{-1,1}\ket{\uparrow}_{2}, |2|ψ1,1|2\ket{\uparrow}_{-2}\ket{\psi^{-}}_{-1,1}\ket{\downarrow}_{2}, |2|ψ1,1|2,\ket{\downarrow}_{-2}\ket{\psi^{-}}_{-1,1}\ket{\uparrow}_{2}, |2|ψ1,1|2}\ket{\downarrow}_{-2}\ket{\psi^{-}}_{-1,1}\ket{\downarrow}_{2}\}. The first-order corrections arise due to the action of the perturbative term on the ground state subspace. This is quantified via the computation of the matrix elements of the effective Hamiltonian to first order

Hα,βeff(1)=mα|V|mβ,H_{\alpha,\beta}^{eff\left(1\right)}=\bra{m_{\alpha}}V\ket{m_{\beta}}, (53)

yielding

Heff(1)=2h2(0000010000100000)H^{eff(1)}=2h_{2}^{\prime}\begin{pmatrix}0&0&0&0\\ 0&1&0&0\\ 0&0&-1&0\\ 0&0&0&0\end{pmatrix} (54)

in the basis {|m}\{\ket{m}\}. By inspection, it can be seen that the first-order effective Hamiltonian term is therefore Heff(1)=h2(σ2zσ2z)H^{eff(1)}=h_{2}^{\prime}(\sigma_{-2}^{z}-\sigma_{2}^{z}). The first-order ground state energy correction is found by diagonalizing the above matrix. It is clear that the degeneracy is only partially lifted to first order. It is therefore necessary to consider the second order corrections that arise due to the overlap with states from each of the excited state subspaces. These excited state subspaces are found in the same way as the set {|m}\{\ket{m}\} by taking the tensor product of the two-qubit computational basis with the excited eigenstates of H0H_{0}: {|s}={|s1,|s2,|s3,|s4}\{\ket{s}\}=\{\ket{s_{1}},\ket{s_{2}},\ket{s_{3}},\ket{s_{4}}\} ={|=\{\ket{\uparrow\uparrow\uparrow\uparrow}, |\ket{\uparrow\uparrow\uparrow\downarrow}, |\ket{\downarrow\uparrow\uparrow\uparrow}, |}\ket{\downarrow\uparrow\uparrow\downarrow}\}, {|t}={|t1,|t2,|t3,|t4}\{\ket{t}\}=\{\ket{t_{1}},\ket{t_{2}},\ket{t_{3}},\ket{t_{4}}\} ={|=\{\ket{\uparrow\downarrow\downarrow\uparrow}, |\ket{\uparrow\downarrow\downarrow\downarrow}, |\ket{\downarrow\downarrow\downarrow\uparrow}, |}\ket{\downarrow\downarrow\downarrow\downarrow}\}, {|k}={|k1,|k2,|k3,|k4}\{\ket{k}\}=\{\ket{k_{1}},\ket{k_{2}},\ket{k_{3}},\ket{k_{4}}\} ={|2|ψ+1,1|2=\{\ket{\uparrow}_{-2}\ket{\psi^{+}}_{-1,1}\ket{\uparrow}_{2}, |2|ψ+1,1|2\ket{\uparrow}_{-2}\ket{\psi^{+}}_{-1,1}\ket{\downarrow}_{2}, |2|ψ+1,1|2\ket{\downarrow}_{-2}\ket{\psi^{+}}_{-1,1}\ket{\uparrow}_{2}, |2|ψ+1,1|2}}\ket{\downarrow}_{-2}\ket{\psi^{+}}_{-1,1}\ket{\downarrow}_{2}\}\}. Such that the full set of excited states, {|n}={{|s},{|t},{|k}}\{\ket{n}\}=\{\{\ket{s}\},\{\ket{t}\},\{\ket{k}\}\}.

The matrix elements of the effective Hamiltonian to second-order are found from

Hα,βeff(2)=i=1mα|V|nini|V|mβEEi.H_{\alpha,\beta}^{eff(2)}=\sum_{i=1}\frac{\bra{m_{\alpha}}V\ket{n_{i}}\bra{n_{i}}V\ket{m_{\beta}}}{E_{-}-E_{i}}. (55)

The computation of which yields

Heff(2)=(2J2)2(1+q12)E1(1+q1200002q122q1002q1200001+q12).H^{eff(2)}=\frac{(2J_{2}^{\prime})^{2}}{(1+q_{1}^{2})E_{1}}\begin{pmatrix}1+q_{1}^{2}&0&0&0\\ 0&2q_{1}^{2}&-2q_{1}&0\\ 0&-2q_{1}&2&0\\ 0&0&0&1+q_{1}^{2}\end{pmatrix}. (56)

Combining our first and second-order perturbative terms we derive an expression for the effective Hamiltonian correct to 𝒪(λ2)\mathcal{O}(\lambda^{2})

Heff\displaystyle H^{eff} E1𝟏4+λHeff(1)+λ2Heff(2)\displaystyle\approx E_{1}\mathbf{1}_{4}+\lambda H^{eff(1)}+\lambda^{2}H^{eff(2)} (57)
=(E1+(2λJ2)2E1)𝟏4\displaystyle=\left(E_{1}+\frac{(2\lambda J_{2}^{\prime})^{2}}{E_{1}}\right)\mathbf{1}_{4} (58)
q1(2λJ2)2(1+q12)E1(σ2xσ2x+σ2yσ2y)\displaystyle\qquad-\frac{q_{1}(2\lambda J_{2}^{\prime})^{2}}{(1+q_{1}^{2})E_{1}}(\sigma_{-2}^{x}\sigma_{2}^{x}+\sigma_{-2}^{y}\sigma_{2}^{y})
+(λh22(1q12)(λJ2)2(1+q12)E1)(σ2zσ2z)\displaystyle\qquad+\left(\lambda h_{2}^{\prime}-\frac{2(1-q_{1}^{2})(\lambda J_{2}^{\prime})^{2}}{(1+q_{1}^{2})E_{1}}\right)(\sigma_{-2}^{z}-\sigma_{2}^{z})
=𝒞𝟏4+J2~(σ2xσ2x+σ2yσ2y)+h~2(σ2zσ2z)\displaystyle=\mathcal{C}\mathbf{1}_{4}+\tilde{J_{2}}(\sigma_{-2}^{x}\sigma_{2}^{x}+\sigma_{-2}^{y}\sigma_{2}^{y})+\tilde{h}_{2}(\sigma_{-2}^{z}-\sigma_{2}^{z}) (59)

In this way we obtain the following expressions for our renormalized parameters

J2~=4J22[2]q12J1,\tilde{J_{2}}=\frac{4J_{2}^{2}}{[2]_{q_{1}}^{2}J_{1}}, (60)
h~2=h22(q11q1)J22[2]q12J1.\tilde{h}_{2}=h_{2}-\frac{2\left(q_{1}-\frac{1}{q_{1}}\right)J_{2}^{2}}{[2]_{q_{1}}^{2}J_{1}}. (61)

Note that, in the case h1=h2=0h_{1}=h_{2}=0 such that q1=q2=1q_{1}=q_{2}=1, h~2\tilde{h}_{2} vanishes and J2~\tilde{J_{2}} returns to that of the inhomogeneous XX model re-scaling as seen in equation (11) as expected.

Diagonalization of the effective Hamiltonian yields the ground state

|ψ\displaystyle\ket{\psi} =1[2]q2(q212|m2q212|m3)\displaystyle=\frac{1}{\sqrt{[2]_{q_{2}}}}\left(q_{2}^{-\frac{1}{2}}\ket{m_{2}}-q_{2}^{\frac{1}{2}}\ket{m_{3}}\right) (62)
=(1[2]q1(q112|1,1q112|1,1))\displaystyle=\left(\frac{1}{\sqrt{[2]_{q_{1}}}}(q_{1}^{-\frac{1}{2}}\ket{\uparrow\downarrow}_{-1,1}-q_{1}^{\frac{1}{2}}\ket{\downarrow\uparrow}_{-1,1})\right) (63)
(1[2]q2(q212|2,2q212|2,2))\displaystyle\qquad\otimes\left(\frac{1}{\sqrt{[2]_{q_{2}}}}(q_{2}^{-\frac{1}{2}}\ket{\uparrow\downarrow}_{-2,2}-q_{2}^{\frac{1}{2}}\ket{\downarrow\uparrow}_{-2,2})\right)

with corresponding ground state energy

E2=E14J22[2]q1J1+E2~,E_{2}=E_{1}-\frac{4J_{2}^{2}}{[2]_{q_{1}}J_{1}}+\tilde{E_{2}}, (64)

where

E2~=[2]q2J2~.\tilde{E_{2}}=-[2]_{q_{2}}\tilde{J_{2}}. (65)

Appendix B Relationship Between Real Model Parameters and Single-Particle Entanglement Energies

In Section III.2 the following relationship was found between the renormalised coupling parameters and single-particle entanglement energies

h~iJi~=sinh(ϵi2).\frac{\tilde{h}_{i}}{\tilde{J_{i}}}=-\sinh{\left(\frac{\epsilon_{i}}{2}\right)}. (66)

By combining this relation with equations (18) and (19), we can obtain expressions that directly relate the desired single-particle entanglement energies to the required ratio of real parameters in our model. The recursive nature of the formulae for the re-scaled parameters means that in order to engineer some single-particle energy ϵi\epsilon_{i} it is necessary to have previously established some value for all previous i1i-1 energies.

In the case J1,h1Ji1,hi1J_{1},h_{1}\gg J_{i\neq 1},h_{i\neq 1} that we consider, the central terms J1J_{1} and h1h_{1} do not get re-scaled, therefore simply

h1=J1sinh(ϵ12),h_{1}=-J_{1}\sinh{\left(\frac{\epsilon_{1}}{2}\right)}, (67)

for some desired single-particle energy, ϵ1\epsilon_{1}, and fixed value of the central coupling term. In Appendix A we have found exact expressions for the renormalized parameters J2~\tilde{J_{2}} and h~2\tilde{h}_{2}. By substituting these into (30) and fixing all other parameters, we obtain an expression for the required transverse field

h2=J22cosh2(ϵ12)J1[sinh(ϵ22)+sinh(ϵ12)].h_{2}=-\frac{J_{2}^{2}}{\cosh^{2}{\left(\frac{\epsilon_{1}}{2}\right)}J_{1}}\left[\sinh{\left(\frac{\epsilon_{2}}{2}\right)}+\sinh{\left(\frac{\epsilon_{1}}{2}\right)}\right]. (68)

Repated iterations of this process yield a general form for the required transverse field parameter for any pair of sites i-i and ii, when i>2i>2

hi>2=Ji2cosh2(ϵi12)hi1[sinh(ϵi2)+sinh(ϵi12)]×[sinh(ϵi12)+sinh(ϵi22)].h_{i>2}=\frac{J_{i}^{2}}{\cosh^{2}\left(\frac{\epsilon_{i-1}}{2}\right)h_{i-1}}\left[\sinh{\left(\frac{\epsilon_{i}}{2}\right)}+\sinh{\left(\frac{\epsilon_{i-1}}{2}\right)}\right]\\ \times\left[\sinh{\left(\frac{\epsilon_{i-1}}{2}\right)}+\sinh{\left(\frac{\epsilon_{i-2}}{2}\right)}\right]. (69)

Thus, it is made explicit how the real parameters of our model can be selected such as to produce any desired set of single-particle entanglement energies.

References